Acrylic Polymer Composition Suitable for Ion Delivery and Selective Detection of Proton, and Hydroxyl and Cu(II) Ions

被引：0
|
作者：
Lee, Dahye [1 ]
Woo, Heejung [1 ]
Do, Jung Yun [1 ]
机构：
[1] Pusan Natl Univ, Dept Chem Educ, Pusan 609735, South Korea
来源：
POLYMER-KOREA | 2014年 / 38卷 / 06期
关键词：
proton transfer in polymer film; UV-polymerizaion; p-methylred; rhodamine; copper(II) ion detection; PH; SENSORS; GREEN; FILMS;
D O I：
10.7317/pk.2014.38.6.801
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Ion diffusion and chemical binding to acrylic polymer were investigated in a solid film. The composition of acrylic monomers containing amino group and carboxylic acid was adjusted for rapid ion migration in the film p-Methylred (PMR) and phenolphthalein derivatives were optically sensitive to the concentration of proton and hydroxyl anion, respectively and verified the ion migration through the film layers. A rapid proton migration was observed in the film of a high amino content. On the other hand, OH- migration occurred rapidly in a high content of carboxylic acid group. The proton migration occurred through the internal layer as well as surface layer of a film and was reversible during 50 repetition examination. Copper(II) ion migration was examined with a Rhodamine-containing polymer film. The light absorption and emission spectra of a Rhodamine-Cu complex showed the key contribution of carboxylic acid group to the Cu(II) migration in a film
引用
收藏
页码：801 / 808
页数：8
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