Recent progress on electrochemical synthesis involving carboxylic acids

被引:48
作者
Chen, Na [1 ]
Ye, Zenghui [1 ]
Zhang, Fengzhi [1 ]
机构
[1] Zhejiang Univ Technol, Coll Pharmaceut Sci, 18 Chaowang Rd, Hangzhou 310014, Zhejiang, Peoples R China
基金
中国国家自然科学基金;
关键词
C-H FUNCTIONALIZATION; OLEFIN COUPLING REACTIONS; ELECTROLYTIC DECARBOXYLATION REACTIONS; CONVERGENT PAIRED ELECTROLYSIS; NON-KOLBE ELECTROLYSIS; REDOX-ACTIVE ESTERS; N BOND FORMATION; ANODIC DECARBOXYLATION; OXIDATIVE DECARBOXYLATION; ELECTROCATALYTIC APPROACH;
D O I
10.1039/d1ob00420d
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Carboxylic acids are not only essential sections of medicinal molecules, natural products and agrochemicals but also basic building blocks for organic synthesis. However, high temperature, expensive catalysts and excess oxidants are normally required for carboxylic acid group transformations. Therefore, more eco-friendly and efficient methods are urgently needed. Organic electrochemistry, as an environmentally friendly and sustainable synthetic method, can potentially avoid the above problems and is favored by more and more organic chemists. This review summarized the recent progress on the electrochemical synthesis of carboxylic acids to construct more complex compounds, emphasizing the development of electrosynthesis methodologies and mechanisms in order to attract more chemists to recognize the importance and applications of electrochemical synthesis.
引用
收藏
页码:5501 / 5520
页数:20
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