Recent Advances in the Synthetic Use of Migration Reactions of Allyl Alcohols

被引：23

作者：

Xing, Yun ^{[1
,2
]}

Li, Chen ^{[3
]}

Meng, Jianping ^{[3
]}

Zhang, Zhen ^{[2
]}

Wang, Xin ^{[2
]}

Wang, Zhichuan ^{[3
]}

Ye, Yong ^{[4
]}

Sun, Kai ^{[2
]}

机构：

[1] Anyang Normal Univ, Coll Chem & Chem Engn, Anyang 455000, Peoples R China

[2] Yantai Univ, Coll Chem & Chem Engn, Yantai 264005, Shandong, Peoples R China

[3] Harbin Univ Commerce, Sch Pharm, Harbin 150076, Peoples R China

[4] Zhengzhou Univ, Coll Chem, Zhengzhou 450001, Peoples R China

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2021年 / 363卷 / 16期

基金：

中国国家自然科学基金;

关键词：

Allyl alcohol; Migration; Rearrangement; Carbonyl compounds; Mechanism; CONCOMITANT 1,2-ARYL MIGRATION; C-H FUNCTIONALIZATION; RING EXPANSION; CATALYZED TRIFLUOROMETHYLATION; SEMIPINACOL REARRANGEMENT; NEOPHYL REARRANGEMENT; CARBONYL-COMPOUNDS; ALKENES; KETONES; ALPHA;

D O I：

10.1002/adsc.202100446

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Allyl alcohol compounds are widely used structural units. In recent years, considerable attention has been devoted to exploring the migration reactions of allyl alcohols via semipinacol or neophyl rearrangements, and so on, providing an attractive and powerful strategy for obtaining various important carbonyl compounds. However, to date, no review has been published that summarizes the significant advances in the preparation of functionalized carbonyl compounds using these migration rearrangement reactions. In this paper, the latest progress in the use of allyl alcohols as flexible synthons involving group migration is introduced, and the reaction scopes, limitations, and some of the mechanisms are also discussed. 1. Introduction 2. Metal-Catalyzed/Induced Migration Rearrangement Reactions 3. Visible Light Promoted Migration Rearrangement Reactions 4. Electrochemically Enabled Migration Rearrangement Reactions 5. Peroxide or Persulfide Induced Migration Rearrangement Reactions 6. Other Migration Rearrangement Reactions 7. Conclusion

引用

页码：3913 / 3936

页数：24

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