Amavadine as a catalyst for the peroxidative halogenation, hydroxylation and oxygenation of alkanes and benzene

被引：94

作者：

Reis, PM ^{[1
]}

Silva, JAL ^{[1
]}

da Silva, JJRF ^{[1
]}

Pombeiro, AJL ^{[1
]}

机构：

[1] Univ Tecn Lisboa, Ctr Quim Estrutural, Inst Super Tecn, P-1049001 Lisbon, Portugal

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 19期

关键词：

D O I：

10.1039/b005513l

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Synthetic amavadine models, [V(HIDPA)(2)](2-) and [V(HIDA)(2)](2-) [where HIDPA and HIDA stand for the basic forms of 2,2'-(hydroxyimino)dipropionic and 2,2'-(hydroxyimino)diacetic acid, respectively], exhibit haloperoxidase- or peroxidase-type activities, and act as catalysts for the selective peroxidative monohalogenation, hydroxylation or oxo-functionalization of alkanes or aromatic compounds such as benzene and mesitylene at room temperature.

引用

页码：1845 / 1846

页数：2

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