Amavadine as a catalyst for the peroxidative halogenation, hydroxylation and oxygenation of alkanes and benzene

被引：94
作者：
Reis, PM [1 ]
Silva, JAL [1 ]
da Silva, JJRF [1 ]
Pombeiro, AJL [1 ]
机构：
[1] Univ Tecn Lisboa, Ctr Quim Estrutural, Inst Super Tecn, P-1049001 Lisbon, Portugal
来源：
CHEMICAL COMMUNICATIONS | 2000年 / 19期
关键词：
D O I：
10.1039/b005513l
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Synthetic amavadine models, [V(HIDPA)(2)](2-) and [V(HIDA)(2)](2-) [where HIDPA and HIDA stand for the basic forms of 2,2'-(hydroxyimino)dipropionic and 2,2'-(hydroxyimino)diacetic acid, respectively], exhibit haloperoxidase- or peroxidase-type activities, and act as catalysts for the selective peroxidative monohalogenation, hydroxylation or oxo-functionalization of alkanes or aromatic compounds such as benzene and mesitylene at room temperature.
引用
收藏
页码：1845 / 1846
页数：2
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