Utilization of Natural Cellulosic African Teff Straw Fiber for Development of Epoxy Composites: Thermal Characterization with Activation Energy Analysis

被引:7
作者
Devnani, G. L. [1 ]
Sinha, Shishir [2 ]
机构
[1] Harcourt Butler Tech Univ, Dept Chem Engn, Kanpur, UP, India
[2] Indian Inst Technol Roorkee, Dept Chem Engn, Roorkee, Uttarakhand, India
关键词
Iso-conversional; activation energy; XPS; cellulosic; XRD; composites; ERAGROSTIS-TEF; DECOMPOSITION KINETICS; BIOCOMPOSITES; LIGHTWEIGHT; EXTRACTION; STABILITY;
D O I
10.1080/15440478.2021.1929646
中图分类号
TB3 [工程材料学]; TS1 [纺织工业、染整工业];
学科分类号
0805 ; 080502 ; 0821 ;
摘要
This article focuses on the utilization of cellulosic fiber African Teff straw, for the fabrication of epoxy composites. 5 and 10% NaOH solution is used for surface treatment of fiber. Compositional and XPS analysis is preformed for untreated and treated fibers and O/C ratio is evaluated. Impact, morphology, crystallinity, thermal characteristics and activation energy of untreated and alkali-treated Epoxy composites reinforced by this fiber are studied. Isoconversional FWO and Friedman are applied for understanding the degradation behavior along with apparent activation energy of composites. 5% alkali-treated composites have improved thermal stability and has apparent activation energy 249 kJ/mol, which is 16% higher compared to untreated composites. Compositional and XPS (X-ray photoelectron spectroscopy) analysis of fiber and characterization of composites along with XRD (X-ray diffraction) analysis also support these findings. Composites reinforced by optimally treated fiber can be utilized for semi structural applications
引用
收藏
页码:6564 / 6575
页数:12
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