Direct synthesis of Zn-incorporated nano-ZSM-5 zeolite by a dry gel conversion method for improving catalytic performance of methanol to aromatics reaction

被引：11

作者：

Wang, Youhe ^{[1
]}

Xu, Jingwei ^{[1
]}

Li, Zhihong ^{[1
,2
]}

Guan, Shuai ^{[1
]}

Zeng, Yuyang ^{[1
]}

Zhao, Guofeng ^{[3
]}

Sun, Hongman ^{[1
]}

Wen, Fushan ^{[2
]}

Subhan, Fazle ^{[1
,4
]}

Yan, Zifeng ^{[1
]}

机构：

[1] China Univ Petr East China, State Key Lab Heavy Oil Proc, Coll Sci, Qingdao 266580, Peoples R China

[2] China Univ Petr East China, Sch Mat Sci & Engn, Qingdao 266580, Peoples R China

[3] East China Normal Univ, Sch Chem & Mol Engn, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China

[4] Abdul Wali Khan Univ, Dept Chem, Mardan, KPK, Pakistan

来源：

JOURNAL OF POROUS MATERIALS | 2021年 / 28卷 / 05期

关键词：

Zn-incorporated nano-ZSM-5 zeolite; Direct synthesis; Dry gel conversion; Methanol to aromatics; BTX; SELECTIVE CONVERSION; ZSM-5; ZEOLITES; TO-HYDROCARBONS; COKE FORMATION; MFI ZEOLITES; AROMATIZATION; CRYSTALLIZATION; DEHYDROGENATION; MESOPOROSITY; DEACTIVATION;

D O I：

10.1007/s10934-021-01120-1

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A series of Zn-incorporated nano-ZSM-5 zeolites were synthesized by a dry gel conversion (DGC) method using tetrapropylammonium hydroxide (TPAOH) as a single template, and their activity in methanol to aromatics (MTA) process was investigated. The characterization results revealed that the introduction of Zn species slightly decreased the crystal size with the formation of some agglomerated particles. We also demonstrated that new Lewis acid sites formed in Zn-incorporated nano-ZSM-5 zeolite at the expense of Bronsted acid sites. The amount of medium acid sites in Zn-modified samples increased with increasing of Zn contents. Catalytic evaluation results revealed that the selectivity of BTX and aromatics for the sample synthesized via direct synthesis (Zn-NZ5-3) is increased from 24.0% and 37.9% to 27.9% and 46.4%, respectively. In addition, the lifetime of the sample prepared by the direct synthesis (Zn-NZ5-3) was 33% longer than that of the impregnated sample, while the selectivity of BTX and aromatics was slightly higher.

引用

页码：1609 / 1618

页数：10

共 36 条

[1]

Chen J, 2001, CHINESE J CATAL+, V22, P229

[2] Modified zeolite ZSM-5 for the methanol to aromatics reaction [J].

Conte, Marco ;

Lopez-Sanchez, Jose A. ;

He, Qian ;

Morgan, David J. ;

Ryabenkova, Yulia ;

Bartley, Jonathan K. ;

Carley, Albert F. ;

Taylor, Stuart H. ;

Kiely, Christopher J. ;

Khalid, Karim ;

Hutchings, Graham J. .

CATALYSIS SCIENCE & TECHNOLOGY, 2012, 2 (01) :105-112

[3] DETERMINATION OF INTEGRATED MOLAR EXTINCTION COEFFICIENTS FOR INFRARED-ABSORPTION BANDS OF PYRIDINE ADSORBED ON SOLID ACID CATALYSTS [J].

EMEIS, CA .

JOURNAL OF CATALYSIS, 1993, 141 (02) :347-354

[4]

Fahim MA, 2010, FUNDAMENTALS OF PETROLEUM REFINING, P95, DOI 10.1016/B978-0-444-52785-1.00005-X

[5] Effect of zinc salt on the synthesis of ZSM-5 for alkylation of benzene with ethanol [J].

Gao, Junhua ;

Zhang, Lidong ;

Hu, Jinxian ;

Li, Wenhuai ;

Wang, Jianguo .

CATALYSIS COMMUNICATIONS, 2009, 10 (12) :1615-1619

[6] A Mechanistic Study of Methanol-to-Aromatics Reaction over Ga-Modified ZSM-5 Zeolites: Understanding the Dehydrogenation Process [J].

Gao, Pan ;

Xu, Jun ;

Qi, Guodong ;

Wang, Chao ;

Wang, Qiang ;

Zhao, Yanxi ;

Zhang, Yuhua ;

Feng, Ningdong ;

Zhao, Xingling ;

Li, Jinlin ;

Deng, Feng .

ACS CATALYSIS, 2018, 8 (10) :9809-9820

[7] Decoupling mesoporosity formation and acidity modification in ZSM-5 zeolites by sequential desilication-dealumination [J].

Groen, JC ;

Moulijn, JA ;

Pérez-Ramírez, J .

MICROPOROUS AND MESOPOROUS MATERIALS, 2005, 87 (02) :153-161

[8] PHOTOCHEMISTRY AND RADIATION-CHEMISTRY OF COLLOIDAL SEMICONDUCTORS .23. ELECTRON STORAGE ON ZNO PARTICLES AND SIZE QUANTIZATION [J].

HAASE, M ;

WELLER, H ;

HENGLEIN, A .

JOURNAL OF PHYSICAL CHEMISTRY, 1988, 92 (02) :482-487

[9] SELECTIVE CONVERSION OF METHANOL INTO AROMATIC-HYDROCARBONS OVER SILVER-EXCHANGED ZSM-5 ZEOLITES [J].

INOUE, Y ;

NAKASHIRO, K ;

ONO, Y .

MICROPOROUS MATERIALS, 1995, 4 (05) :379-383

[10] Pt-Zn/HZSM-5 as a highly selective catalyst for the Co-aromatization of methane and light straight run naphtha [J].

Jarvis, Jack ;

He, Peng ;

Wang, Aiguo ;

Song, Hua .

FUEL, 2019, 236 :1301-1310

← 1 2 3 4 →