Water Molecules as Binders in Transformation of 2D Coordination Polymer [Cu(4,4′-bpy)2(OTf)2]n into Parallel Aligned 3D Architectures

被引：6
|
作者：
Komori-Orisaku, Keiko [1 ]
Hoshino, Kazuma [1 ]
Yamashita, Shinya [1 ]
Koide, Yoshihiro [1 ]
机构：
[1] Kanagawa Univ, Dept Mat & Life Chem, Yokohama, Kanagawa 2218686, Japan
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2010年 / 83卷 / 03期
关键词：
METAL-ORGANIC FRAMEWORK; ZEOLITIC IMIDAZOLATE FRAMEWORKS; SELF-ASSEMBLED MONOLAYERS; BUILDING-BLOCKS; TRANSITION; CLUSTER; ADSORPTION; CATALYSIS; SORPTION; GROWTH;
D O I：
10.1246/bcsj.20090244
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Solvent-mediated structural transformation of {[Cu(4,4'-bpy)(2)(OTf)(2)]center dot CH3CN}(n) coordination polymer (CP) was crystallographically characterized and confirmed the formation of infinite linear water networks that bind metal centers through the intemlay of coordination and hydrogen bonding of water molecules.
引用
收藏
页码：276 / 278
页数：3
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