Examples of molecular switching in inorganic solids, due to temperature, light, pressure, and magnetic field

被引:44
作者
Varret, F
Bleuzen, A
Boukheddaden, K
Bousseksou, A
Codjovi, E
Enachescu, C
Goujon, A
Linares, J
Menendez, N
Verdaguer, M
机构
[1] Univ Versailles, CNRS, Lab Magnetisme & Opt, F-78035 Versailles, France
[2] Univ Paris 06, CNRS, Lab Chim Inorgan & Mat Mol, F-75252 Paris 05, France
[3] CNRS, Chim Coordinat Lab, UPR 8241, F-31017 Toulouse, France
[4] Univ Autonoma Madrid, Dept Quim Fis Aplicada, E-28049 Madrid, Spain
关键词
D O I
10.1351/pac200274112159
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We describe various molecular switching processes occurring in several types of inorganic solids: spin cross-over (SC) compounds, photomagnetic Prussian blue analogs (PBAs), and valence-tautomeric system. Their thermo-, photo-, piezo-, and magneto-chromic properties are illustrated by recent examples. A common description of their static properties by a two-level model is given.
引用
收藏
页码:2159 / 2168
页数:10
相关论文
共 66 条
  • [1] PHOTOINDUCED VALENCE TAUTOMERISM IN COBALT COMPLEXES CONTAINING SEMIQUINONE ANION AS LIGAND - DYNAMICS OF THE HIGH-SPIN [COII(3,5-DTBSQ)(2)] TO LOW-SPIN [CO-III(3,5-DTBSQ)(3,5-DTBCAT)] INTERCONVERSION
    ADAMS, DM
    LI, BL
    SIMON, JD
    HENDRICKSON, DN
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (13-14): : 1481 - 1483
  • [2] Pulsed laser photolysis and thermodynamics studies of intramolecular electron transfer in valence tautomeric cobalt o-quinone complexes
    Adams, DM
    Hendrickson, DN
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (46) : 11515 - 11528
  • [3] AMMETER JH, 1980, NOUV J CHIM, V4, P631
  • [4] Photoinduced ferrimagnetic systems in Prussian blue analogues Cx(I)Co4[Fe(CN)6]y (CI = alkali cation).: 1.: Conditions to observe the phenomenon
    Bleuzen, A
    Lomenech, C
    Escax, V
    Villain, F
    Varret, F
    Moulin, CCD
    Verdaguer, M
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (28) : 6648 - 6652
  • [5] First ligand-driven light-induced spin change at room temperature in a transition-metal molecular compound
    Boillot, ML
    Chantraine, S
    Zarembowitch, J
    Lallemand, JY
    Prunet, J
    [J]. NEW JOURNAL OF CHEMISTRY, 1999, 23 (02) : 179 - 183
  • [6] Pressure-induced spin-state crossovers at room temperature in iron(II) complexes:: comparative analysis;: a XANES investigation of some new transitions
    Boillot, ML
    Zarembowitch, J
    Itié, JP
    Polian, A
    Bourdet, E
    Haasnoot, JG
    [J]. NEW JOURNAL OF CHEMISTRY, 2002, 26 (03) : 313 - 322
  • [7] One-dimensional Ising-like systems: an analytical investigation of the static and dynamic properties, applied to spin-crossover relaxation
    Boukheddaden, K
    Linares, J
    Spiering, H
    Varret, F
    [J]. EUROPEAN PHYSICAL JOURNAL B, 2000, 15 (02) : 317 - 326
  • [8] BOUSSEKSOU A, 1995, J PHYS I, V5, P747, DOI 10.1051/jp1:1995165
  • [9] BOUSSEKSOU A, 1992, J PHYS I, V2, P1381, DOI 10.1051/jp1:1992217
  • [10] Ising-like model for the two step spin-crossover of binuclear molecules
    Bousseksou, A.
    Varret, F.
    Nasser, J.
    [J]. Journal De Physique, I, 1993, 3 (06):