Examples of molecular switching in inorganic solids, due to temperature, light, pressure, and magnetic field

被引:44
作者
Varret, F
Bleuzen, A
Boukheddaden, K
Bousseksou, A
Codjovi, E
Enachescu, C
Goujon, A
Linares, J
Menendez, N
Verdaguer, M
机构
[1] Univ Versailles, CNRS, Lab Magnetisme & Opt, F-78035 Versailles, France
[2] Univ Paris 06, CNRS, Lab Chim Inorgan & Mat Mol, F-75252 Paris 05, France
[3] CNRS, Chim Coordinat Lab, UPR 8241, F-31017 Toulouse, France
[4] Univ Autonoma Madrid, Dept Quim Fis Aplicada, E-28049 Madrid, Spain
关键词
D O I
10.1351/pac200274112159
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We describe various molecular switching processes occurring in several types of inorganic solids: spin cross-over (SC) compounds, photomagnetic Prussian blue analogs (PBAs), and valence-tautomeric system. Their thermo-, photo-, piezo-, and magneto-chromic properties are illustrated by recent examples. A common description of their static properties by a two-level model is given.
引用
收藏
页码:2159 / 2168
页数:10
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