Face Centred Cubic Multi-Component Equiatomic Solid Solutions in the Au-Cu-Ni-Pd-Pt System

被引:30
作者
Freudenberger, Jens [1 ,2 ]
Rafaja, David [2 ]
Geissler, David [1 ]
Giebeler, Lars [1 ]
Ullrich, Christiane [2 ]
Kauffmann, Alexander [3 ]
Heilmaier, Martin [3 ]
Nielsch, Kornelius [1 ,4 ]
机构
[1] Leibniz Inst Solid State & Mat Res Dresden IFW Dr, Helmholtzstr 20, D-01069 Dresden, Germany
[2] TU Bergakad Freiberg, Inst Mat Sci, Gustav Zeuner Str 5, D-09596 Freiberg, Germany
[3] Karlsruhe Inst Technol, Inst Appl Mat IAM WK, Engelbert Arnold Str 4, D-76131 Karlsruhe, Germany
[4] Tech Univ Dresden, Inst Mat Sci, D-01062 Dresden, Germany
关键词
soild solution; segregation; high entropy alloy; XRD line broadening; X-RAY-DIFFRACTION; HIGH-ENTROPY ALLOYS; MECHANICAL-PROPERTIES; MICROSTRUCTURE; STEELS; HOT;
D O I
10.3390/met7040135
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A single-phase solid solution is observed in quaternary and quinary alloys obtained from gold, copper, nickel, palladium and platinum. The lattice parameters of the alloys follow the linear rule of mixture when considering the lattice parameters of the elements and their concentration. The elements are a priori not homogeneously distributed within the respective alloys resulting in segregations. These segregations cause a large broadening of X-ray lines, which is accessed in the present article. This correlation is visualized by the help of local element mappings utilizing scanning electron microscopy including energy dispersive X-ray analysis and their quantitative analysis.
引用
收藏
页数:18
相关论文
共 30 条
[1]   Microstructural development in equiatomic multicomponent alloys [J].
Cantor, B ;
Chang, ITH ;
Knight, P ;
Vincent, AJB .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2004, 375 :213-218
[2]   Hexagonal High-entropy Alloys [J].
Feuerbacher, Michael ;
Heidelmann, Markus ;
Thomas, Carsten .
MATERIALS RESEARCH LETTERS, 2015, 3 (01) :1-6
[3]   Single-phase high-entropy alloys - an overview [J].
Kozak, Roksolana ;
Sologubenko, Alla ;
Steurer, Walter .
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-CRYSTALLINE MATERIALS, 2015, 230 (01) :55-68
[4]   Structural-disorder and its effect on mechanical properties in single-phase TaNbHfZr high-entropy alloy [J].
Maiti, Soumyadipta ;
Steurer, Walter .
ACTA MATERIALIA, 2016, 106 :87-97
[5]   A critical review of high entropy alloys and related concepts [J].
Miracle, D. B. ;
Senkov, O. N. .
ACTA MATERIALIA, 2017, 122 :448-511
[6]   High-entropy alloys: a critical assessment of their founding principles and future prospects [J].
Pickering, E. J. ;
Jones, N. G. .
INTERNATIONAL MATERIALS REVIEWS, 2016, 61 (03) :183-202
[7]  
Prince E., 2006, International Tables for Crystallography, Volume C: Mathematical, Physical and Chemical Tables, V(ed), DOI DOI 10.1107/97809553602060000103
[8]   Effect of Internal Interfaces on Hardness and Thermal Stability of Nanocrystalline Ti0.5Al0.5N Coatings [J].
Rafaja, D. ;
Wuestefeld, C. ;
Baehtz, C. ;
Klemm, V. ;
Dopita, M. ;
Motylenko, M. ;
Michotte, C. ;
Kathrein, M. .
METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 2011, 42A (03) :559-569
[9]  
Rafaja D., 2000, MATER STRUCT, V7, P43
[10]   Analysis of local composition gradients in the hard-phase grains of cermets using a combination of X-ray diffraction and electron microscopy [J].
Rafaja, David ;
Dopita, Milan ;
Masimov, Magsud ;
Klemm, Volker ;
Wendt, Nina ;
Lengauer, Walter .
INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS, 2008, 26 (03) :263-275