Finite element evaluation of diffusion and dispersion tensors in periodic porous media with advection

This paper presents three-dimensional finite element simulations to evaluate diffusion and dispersion tensors in periodic porous media in the presence of an advective velocity field. These tensors are evaluated in the framework of the double-scale expansion technique. Two problems, a Newtonian flow and a vector-valued advection-diffusion equation, have to be sequentially solved at the pore scale. Finite element techniques to approximate these problems are proposed and analyzed. Numerical results in three-dimensional networks of spheres are presented to quantitatively assess the impact of the pore morphology and of the advection velocity on the diffusion and dispersion tensors.