Preparation and characterization of a novel pH-, thermo-, and ionic strength-responsive hydrogels based on xanthan gum-poly(aspartic acid)

被引:17
作者
Yang, Jun [1 ]
Fang, Li [1 ]
Wang, Fang [1 ]
Tan, Tianwei [1 ]
机构
[1] Beijing Univ Chem Technol, Beijing Key Lab Bioproc, Beijing 100029, Peoples R China
关键词
hydrogels; poly(aspartic acid); xanthan gum; stimuli-sensitive polymers; swelling;
D O I
10.1002/app.25571
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A series of interpenetrating polymer networks (IPN) hydrogels with different compositions that based on xanthan gum (XG) and poly(aspartic acid) (PASP) were synthesized. The effects of various external surrounding stimuli, including pH, temperature, and ionic strength on XG-PASP hydrogels swelling properties were investigated. Chemical structural changes of the IPN hydrogels were characterized by Fourier transform infrared spectroscopy (FT-IR), differential scanning calorimetry (DSC), transmission electron microscopy (TEM), and swelling ratio measurement. The swelling process was found to be a Fickian diffusion and reached swelling equilibrium quickly. It was found that the feed composition of PASP was an important factor that affected the properties of IPN hydrogels. (c) 2007 Wiley Periodicals, Inc.
引用
收藏
页码:539 / 546
页数:8
相关论文
共 16 条
  • [1] [Anonymous], 2011, J MATER CHEM, DOI DOI 10.1039/c1jm10277j
  • [2] Influence of xanthan gum on physical characteristics of heat-denatured whey protein solutions and gels
    Bryant, CM
    McClements, DJ
    [J]. FOOD HYDROCOLLOIDS, 2000, 14 (04) : 383 - 390
  • [3] CARENZA M, 1992, RADIAT PHYS CHEM, V39, P485
  • [4] Bioartificial polymeric materials based on polysaccharides
    Cascone, MG
    Barbani, N
    Cristallini, C
    Giusti, P
    Ciardelli, G
    Lazzeri, L
    [J]. JOURNAL OF BIOMATERIALS SCIENCE-POLYMER EDITION, 2001, 12 (03) : 267 - 281
  • [5] CHOONGKYUN Y, 1996, J MEMBRANE SCI, V109, P257
  • [6] INFLUENCE OF CO-POLYMER COMPOSITION ON NON-FICKIAN WATER TRANSPORT THROUGH GLASSY CO-POLYMERS
    FRANSON, NM
    PEPPAS, NA
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 1983, 28 (04) : 1299 - 1310
  • [7] HEE KJ, 2001, POLYMER, V42, P6851
  • [8] JUN Y, 2006, J APPL POLYM SCI, V102, P550
  • [9] Properties and applications of xanthan gum
    Katzbauer, B
    [J]. POLYMER DEGRADATION AND STABILITY, 1998, 59 (1-3) : 81 - 84
  • [10] Interpenetrating polymer network hydrogels based on poly(ethylene glycol) macromer and chitosan
    Lee, SJ
    Kim, SS
    Lee, YM
    [J]. CARBOHYDRATE POLYMERS, 2000, 41 (02) : 197 - 205