An investigation on pollutant emissions from co-firing of RDF and coal

被引:42
作者
Chyang, Chien-Song [1 ]
Han, Yun-Long [2 ]
Wu, Li-Wei [1 ]
Wan, Hou-Peng [3 ]
Lee, Hom-Ti [3 ]
Chang, Ying-Hsi [3 ]
机构
[1] Chung Yuan Christian Univ, Dept Chem Engn, Chungli 32023, Taiwan
[2] Anhui Univ Technol, Sch Civil Engn & Architecture, Maanshan 243002, Peoples R China
[3] Ind Technol Res Inst, Energy & Environm Lab, Hsinchu 31040, Taiwan
关键词
REFUSE-DERIVED FUEL; CIRCULATING FLUIDIZED-BED; MUNICIPAL SOLID-WASTE; DIBENZO-P-DIOXINS; FLUE-GAS; COMBUSTION; CHLORINE; INCINERATION; BEHAVIOR; COCOMBUSTION;
D O I
10.1016/j.wasman.2009.11.018
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Pollutant emissions from co-firing of refuse derived fuel (RDF) and coal were investigated in a vortexing fluidized bed combustor (VFBC). RDF-5 was made of common municipal solid waste (MSW). CaCO(3) was injected in the combustor to absorb HCl at 850 degrees C. The results show that NO and HCl emissions increase with RDF-5 co-firing ratio. The NO(x) concentration in flue gas at the bottom of the combustor is higher than that at the top. However, the trend of HCl released is reverse compared with NO(x) emissions. It was found that the HCl concentration decreases with increasing the molar ratio of Ca/Cl. However, the effect of CaCO(3) addition on HCl retention is not significant when the molar ratio of Ca/Cl is higher than 5. The chlorine content in fly ash increases obviously with the molar ratio of Ca/Cl. PCDD/Fs emissions decrease slightly with an addition of CaCO3. In this study incomplete combustion is regarded as the main cause for polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) formation. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1334 / 1340
页数:7
相关论文
共 29 条
  • [21] Axial concentration profiles and NO flue gas in a pilot-scale bubbling fluidized bed coal combustor
    Tarelho, LAC
    Matos, MAA
    Pereira, FJMA
    [J]. ENERGY & FUELS, 2004, 18 (06) : 1615 - 1624
  • [22] Vesterinen R, 1996, CHEMOSPHERE, V32, P681, DOI 10.1016/0045-6535(95)00343-6
  • [23] Emissions during co-firing of RDF-5 with bituminous coal, paper sludge and waste tires in a commercial circulating fluidized bed co-generation boiler
    Wan, Hou-Peng
    Chang, Ying-Hsi
    Chien, Wen-Cheng
    Lee, Hoin-Ti
    Huang, C. C.
    [J]. FUEL, 2008, 87 (06) : 761 - 767
  • [24] Pyrolysis and combustion of refuse-derived fuels in a spouting-moving bed reactor
    Wang, ZQ
    Huang, H
    Li, HB
    Wu, CZ
    Chen, Y
    [J]. ENERGY & FUELS, 2002, 16 (01) : 136 - 142
  • [25] Release of Sulfur and Chlorine during Cofiring RDF and Coal in an Internally Circulating Fluidized Bed
    Wei, Xiaolin
    Wang, Yang
    Liu, Dianfu
    Sheng, Hongzhi
    Tian, Wendong
    Xiao, Yunhan
    [J]. ENERGY & FUELS, 2009, 23 (3-4) : 1390 - 1397
  • [26] HYDROGEN-CHLORIDE REACTION WITH LIME AND LIMESTONE - KINETICS AND SORPTION CAPACITY
    WEINELL, CE
    JENSEN, PI
    DAMJOHANSEN, K
    LIVBJERG, H
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1992, 31 (01) : 164 - 171
  • [27] The influence of level and chlorine source on the formation of mono- to octa-chlorinated dibenzo-p-dioxins, dibenzofurans and coplanar polychlorinated biphenyls during combustion of an artificial municipal waste
    Wikström, E
    Marklund, S
    [J]. CHEMOSPHERE, 2001, 43 (02) : 227 - 234
  • [28] YAN CF, 2006, RANLIAO HUAXUE XUEBA, V34, P422
  • [29] ZHAO S, 2005, RANLIAO HUAXUE XUEBA, V33, P633