An investigation on pollutant emissions from co-firing of RDF and coal

被引:42
作者
Chyang, Chien-Song [1 ]
Han, Yun-Long [2 ]
Wu, Li-Wei [1 ]
Wan, Hou-Peng [3 ]
Lee, Hom-Ti [3 ]
Chang, Ying-Hsi [3 ]
机构
[1] Chung Yuan Christian Univ, Dept Chem Engn, Chungli 32023, Taiwan
[2] Anhui Univ Technol, Sch Civil Engn & Architecture, Maanshan 243002, Peoples R China
[3] Ind Technol Res Inst, Energy & Environm Lab, Hsinchu 31040, Taiwan
关键词
REFUSE-DERIVED FUEL; CIRCULATING FLUIDIZED-BED; MUNICIPAL SOLID-WASTE; DIBENZO-P-DIOXINS; FLUE-GAS; COMBUSTION; CHLORINE; INCINERATION; BEHAVIOR; COCOMBUSTION;
D O I
10.1016/j.wasman.2009.11.018
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Pollutant emissions from co-firing of refuse derived fuel (RDF) and coal were investigated in a vortexing fluidized bed combustor (VFBC). RDF-5 was made of common municipal solid waste (MSW). CaCO(3) was injected in the combustor to absorb HCl at 850 degrees C. The results show that NO and HCl emissions increase with RDF-5 co-firing ratio. The NO(x) concentration in flue gas at the bottom of the combustor is higher than that at the top. However, the trend of HCl released is reverse compared with NO(x) emissions. It was found that the HCl concentration decreases with increasing the molar ratio of Ca/Cl. However, the effect of CaCO(3) addition on HCl retention is not significant when the molar ratio of Ca/Cl is higher than 5. The chlorine content in fly ash increases obviously with the molar ratio of Ca/Cl. PCDD/Fs emissions decrease slightly with an addition of CaCO3. In this study incomplete combustion is regarded as the main cause for polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) formation. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1334 / 1340
页数:7
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