A novel norditerpene from Eupatorium adenophorum

被引：4
|
作者：
Wang, Ming-Zhong [1 ]
Cai, Xiang-Hai [1 ]
Du, Guo-Shun [1 ]
Luo, Xiao-Dong [1 ]
机构：
[1] Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources W China, Kunming 650204, Yunnan, Peoples R China
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2007年 / 62卷 / 04期
基金：
中国国家自然科学基金;
关键词：
(4aR,7R,8S,8aR)-1,2,4a,5,6,7,8,8a-octahydro-8-[3-methylenebut-4-alyl]-4,4a,7,8-tetramethylnaphthalen-2(IH)-one; Eupatorium adenophorum; biodegradation; clerodane;
D O I：
10.1515/znb-2007-0416
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel norditerpene was isolated from the flower of Eupatorium adenophorum, named (4aR,7R,8S,8aR)- 1,2,4a,5,6,7,8,8a-octahydro-8-[3-methylenebut-4-alyl]-4,4a,7,8-tetramethylnaphthalen-2(1H)-one (1). Its structure was established by extensive NMR experiments. Based on the diversity of the side chains, a possible biodegradation pathway for the compound from the clerodane skeletone is proposed.
引用
收藏
页码：577 / 579
页数：3
相关论文
共 50 条
  • [1] Cadinene derivatives from Eupatorium adenophorum
    Wang, Ming-Zhong
    Zhang, Yan-Yan
    Li, Shun-n Li
    Cai, Xiang-Hai
    Luo, Xiao-Dong
    HELVETICA CHIMICA ACTA, 2006, 89 (12) : 3104 - 3108
  • [2] A new Sequiterpenoid from Eupatorium adenophorum Spreng
    He Lan
    Yang Jie
    Cao Ao-Cheng
    Liu Yu-Mei
    An Yu
    Shi Jian-Gong
    CHINESE JOURNAL OF CHEMISTRY, 2006, 24 (10) : 1375 - 1377
  • [3] Cadinane sesquiterpenes from the leaves of Eupatorium adenophorum
    He, Lan
    Hou, Jing
    Gan, Maoluo
    Shi, Jiangong
    Chantrapromma, Suchada
    Fun, Hoong-Kun
    Williams, Ian D.
    Sung, Herman H. -Y.
    JOURNAL OF NATURAL PRODUCTS, 2008, 71 (08): : 1485 - 1488
  • [4] Extraction and isolation of β-elemene from eupatorium adenophorum
    Wei, Hui-Ping
    Mu, Zhao
    Yong, L.
    Liu, Weng-Quan
    Journal of Chemical and Pharmaceutical Research, 2014, 6 (05) : 161 - 165
  • [5] Identification of Diverse Sesquiterpenoids from Eupatorium adenophorum
    Gu, Wen-Jie
    Luo, Jia-Hui
    Yang, Yong-Xun
    Geng, Hao
    RECORDS OF NATURAL PRODUCTS, 2024, 18 (02) : 237 - 244
  • [6] Defensive Sesquiterpenoids from Leaves of Eupatorium adenophorum
    Shi Wei
    Luo Shihong
    Li Shenghong
    CHINESE JOURNAL OF CHEMISTRY, 2012, 30 (06) : 1331 - 1334
  • [7] Eupatoranolide, a New Sesquiterpene Lactone from Eupatorium adenophorum
    Zhi Hui DING
    Jing Kai DING(Laboratory of phytochemistry
    ChineseChemicalLetters, 1999, (06) : 491 - 494
  • [8] Hepatotoxicity of Eupatorium adenophorum to rats
    Katoch, R
    Sharma, OP
    Dawra, RK
    Kurade, NP
    TOXICON, 2000, 38 (02) : 309 - 314
  • [9] Eupatoranolide, a new sesquiterpene lactone from Eupatorium adenophorum
    Ding, ZH
    Ding, JK
    CHINESE CHEMICAL LETTERS, 1999, 10 (06) : 491 - 494
  • [10] Cadinene sesquiterpenes from Eupatorium adenophorum and their antifungal activity
    Kundu, Aditi
    Saha, Supradip
    Walia, Suresh
    Shakil, Najam A.
    Kumar, Jitendra
    Annapurna, Kannepalli
    JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART B-PESTICIDES FOOD CONTAMINANTS AND AGRICULTURAL WASTES, 2013, 48 (06) : 516 - 522
12345