Reduction of nitrosobenzenes to azoarenes with SmI2

被引：0

作者：

Ye, Wei ^{[1
]}

Ding, Wenbo ^{[1
]}

Hu, Zhang ^{[2
]}

Yu, Yongping ^{[1
]}

Zou, Hongbin ^{[1
,3
]}

机构：

[1] Zhejiang Univ, Coll Pharmaceut Sci, Hangzhou 310058, Zhejiang, Peoples R China

[2] Guangdong Ocean Univ, Coll Sci, Zhanjiang 524088, Peoples R China

[3] Chinese Acad Sci, Shanghai Inst Mat Med, State Key Lab Drug Res, Beijing 100864, Peoples R China

来源：

JOURNAL OF CHEMICAL RESEARCH | 2010年 / 04期

关键词：

nitrosobenzene; azoarenes; SmI2; NITRO-COMPOUNDS; DERIVATIVES; AZOXY;

D O I：

10.3184/030823410X12706553325118

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel method was developed to synthesise azoarenes from nitrosobenzenes under mild conditions. Samarium (II) iodine was used to achieve the N-N coupling. The method also provides evidence for the proposed mechanism involved in the reduction of nitro compounds to the amines with SmI2.

引用

页码：214 / 215

页数：2

共 16 条

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