Tensile Mechanical Behaviors of High Loading of Carbon Nanotube/Epoxy Composites via Experimental and Finite Element Analysis

被引:3
作者
Shen, Lulu [1 ]
Liu, Ling [1 ]
Wu, Zhanjun [2 ]
机构
[1] Tongji Univ, Sch Aerosp Engn & Appl Mech, Shanghai 200092, Peoples R China
[2] Dalian Univ Technol, State Key Lab Struct Anal Ind Equipment, Sch Aeronaut & Astronaut, Dalian 116024, Liaoning, Peoples R China
关键词
carbon nanotubes; composites; epoxy; tensile mechanical properties; RAMAN-SCATTERING; NANOCOMPOSITES; DISPERSION; MATRIX; BUCKYPAPER; DEFORMATION; ALIGNMENT; NETWORKS; ARRAYS;
D O I
10.1002/adem.201900895
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
This article aims to explore the tensile behaviors of a randomly distributed carbon nanotube (CNT) reinforced epoxy (EP) composite with high CNT loading by experimental and finite element analysis (FEA). The CNT/EP with CNT loading of 22-25 wt% is prepared by resin-film infusion process. The obtained tensile strength and modulus of the as-prepared CNT/EP are increased by 141.7% and 175.3%, respectively, compared with the blank EP. When the CNT/EP prepreg (uncured) is prestretched with a tensile deformation of 2.5% to improve the alignment of CNTs, the yielded tensile strength and modulus of the cured composite are further improved by 6.3% and 10.8%. FEA result reveals that CNTs are the main stress carriers, and the maximum stress level undertaken by CNTs is 23-fold that of EP matrix. Also, the carrying capacity of CNTs is closely correlative to their alignments, when the orientation angle between CNTs' axes and loading direction is changed from 0 degrees to 61 degrees, CNTs bear continuously decreasing tensile stress; otherwise (61 degrees to 90 degrees), CNTs undertake increasing compressive stress. Moreover, CNTs affect their nearby stress fields within EP in a distance of 50-60 nm, which proves that stress can be effectively transferred from EP matrix to CNTs.
引用
收藏
页数:9
相关论文
共 56 条
[2]   ALIGNED CARBON NANOTUBE ARRAYS FORMED BY CUTTING A POLYMER RESIN-NANOTUBE COMPOSITE [J].
AJAYAN, PM ;
STEPHAN, O ;
COLLIEX, C ;
TRAUTH, D .
SCIENCE, 1994, 265 (5176) :1212-1214
[3]   Square representative volume elements for evaluating the effective material properties of carbon nanotube-based composites [J].
Chen, XL ;
Liu, YJ .
COMPUTATIONAL MATERIALS SCIENCE, 2004, 29 (01) :1-11
[4]   Chemical attachment of organic functional groups to single-walled carbon nanotube material [J].
Chen, Y ;
Haddon, RC ;
Fang, S ;
Rao, AM ;
Lee, WH ;
Dickey, EC ;
Grulke, EA ;
Pendergrass, JC ;
Chavan, A ;
Haley, BE ;
Smalley, RE .
JOURNAL OF MATERIALS RESEARCH, 1998, 13 (09) :2423-2431
[5]   Carbon nanotube/epoxy composites fabricated by resin transfer molding [J].
Cheng, Q. F. ;
Wang, J. P. ;
Wen, J. J. ;
Liu, C. H. ;
Jiang, K. L. ;
Li, Q. Q. ;
Fan, S. S. .
CARBON, 2010, 48 (01) :260-266
[6]   High Mechanical Performance Composite Conductor: Multi-Walled Carbon Nanotube Sheet/Bismaleimide Nanocomposites [J].
Cheng, Qunfeng ;
Bao, Jianwen ;
Park, JinGyu ;
Liang, Zhiyong ;
Zhang, Chuck ;
Wang, Ben .
ADVANCED FUNCTIONAL MATERIALS, 2009, 19 (20) :3219-3225
[7]   Small but strong: A review of the mechanical properties of carbon nanotube-polymer composites [J].
Coleman, Jonathan N. ;
Khan, Umar ;
Blau, Werner J. ;
Gun'ko, Yurii K. .
CARBON, 2006, 44 (09) :1624-1652
[8]   Investigation into the deformation of carbon nanotubes and their composites through the use of Raman spectroscopy [J].
Cooper, CA ;
Young, RJ ;
Halsall, M .
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING, 2001, 32 (3-4) :401-411
[9]   Synthesis of epoxy composites with high carbon nanotube loading and effects of tubular and wavy morphology on composite strength and modulus [J].
Feng, Qing-Ping ;
Shen, Xiao-Jun ;
Yang, Jiao-Ping ;
Fu, Shao-Yun ;
Mai, Yiu-Wing ;
Friedrich, Klaus .
POLYMER, 2011, 52 (26) :6037-6045
[10]   Influence of different carbon nanotubes on the mechanical properties of epoxy matrix composites - A comparative study [J].
Gojny, FH ;
Wichmann, MHG ;
Fiedler, B ;
Schulte, K .
COMPOSITES SCIENCE AND TECHNOLOGY, 2005, 65 (15-16) :2300-2313