Optimization of microwave plasma treatment conditions on polydimethylsiloxane films for further surface functionalization

被引:10
作者
Aymes-Chodur, Caroline [1 ]
Salmi-Mani, Hanene [1 ]
Dragoe, Diana [1 ]
Aubry-Barroca, Nadine [1 ]
Buchotte, Marie [1 ]
Roger, Philippe [1 ]
机构
[1] Univ Paris Saclay, Inst Chim Mol & Mat Orsay ICMMO, CNRS, UMR 8182, F-91405 Orsay, France
关键词
PDMS; Microwave plasma; Surface functionalization; Thiol-ene polymerization; 2P CORE-LEVEL; OXYGEN-PLASMA; GRAFT-POLYMERIZATION; HYDROPHOBIC RECOVERY; SILICONE-RUBBER; PRESSURE PLASMA; FREE-ENERGY; PDMS; GLASS; IRRADIATION;
D O I
10.1016/j.eurpolymj.2021.110416
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Polydimethylsiloxane (PDMS) was surface functionalized by a 3-steps process. Firstly, the PDMS surface was activated by means of a microwave Ar/O-2 plasma treatment, that was optimized in this paper. Secondly, the activated surface reacted with mercaptosilanes and finally a thiol-ene photopolymerization of a vanillin derivative monomer was performed. The bio-based monomer was used with the aim of giving antibacterial and antifouling properties to the PDMS surface. Grafting and photopolymerization were successfully evidenced by different analytical means and especially X-Ray Photoelectron Spectroscopy.
引用
收藏
页数:12
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共 75 条
[51]   Adhesive-free adhesion between heat-assisted plasma-treated fluoropolymers (PTFE, PFA) and plasma-jet-treated polydimethylsiloxane (PDMS) and its application [J].
Ohkubo, Yuji ;
Endo, Katsuyoshi ;
Yamamura, Kazuya .
SCIENTIFIC REPORTS, 2018, 8
[52]   Conversion of some siloxane polymers to silicon oxide by UV/ozone photochemical processes [J].
Ouyang, M ;
Yuan, C ;
Muisener, RJ ;
Boulares, A ;
Koberstein, JT .
CHEMISTRY OF MATERIALS, 2000, 12 (06) :1591-1596
[53]   ESTIMATION OF SURFACE FREE ENERGY OF POLYMERS [J].
OWENS, DK ;
WENDT, RC .
JOURNAL OF APPLIED POLYMER SCIENCE, 1969, 13 (08) :1741-&
[54]   Gamma irradiation of silicones [J].
Palsule, Aniruddha S. ;
Clarson, Stephen J. ;
Widenhouse, Christopher W. .
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2008, 18 (02) :207-221
[55]   Kinetics of decay of methyl radicals in irradiated dimethylsilanediol and polymethylsiloxanes [J].
Pankratova, Lidiya N. ;
Saenko, Elizaveta V. ;
Bugaenko, Vladislav L. ;
Makhlyarchuk, Valentin V. .
MENDELEEV COMMUNICATIONS, 2011, 21 (03) :157-159
[56]   Poly(dimethyl siloxane) surface modification by low pressure plasma to improve its characteristics towards biomedical applications [J].
Pinto, S. ;
Alves, P. ;
Matos, C. M. ;
Santos, A. C. ;
Rodrigues, L. R. ;
Teixeira, J. A. ;
Gil, M. H. .
COLLOIDS AND SURFACES B-BIOINTERFACES, 2010, 81 (01) :20-26
[57]   Surface treatment of biomaterials by gamma and swift heavy ions grafting [J].
Porté-Durrieu, MC ;
Aymes-Chodur, C ;
Vergne, C ;
Betz, N ;
Baquey, C .
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 1999, 151 (1-4) :404-415
[58]   Surface modification of polydimethylsiloxane microchannel using air plasma for DNA capillary migration in polydimethylsiloxane-glass microfluidic devices [J].
Rad, Maryam Alsadat ;
Ibrahim, Kamarulazizi ;
Mohamed, Khairudin ;
Najimudin, Nazalan .
MICRO & NANO LETTERS, 2013, 8 (06) :305-307
[59]   Poly(ethylene terephthalate) films modified by UV-induced surface graft polymerization of vanillin derived monomer for antibacterial activity [J].
Salmi-Mani, Hanene ;
Terreros, Gabriel ;
Barroca-Aubry, Nadine ;
Aymes-Chodur, Caroline ;
Regeard, Christophe ;
Roger, Philippe .
EUROPEAN POLYMER JOURNAL, 2018, 103 :51-58
[60]   UV-irradiation induced modification of PDMS films investigated by XPS and spectroscopic ellipsometry [J].
Schnyder, B ;
Lippert, T ;
Kötz, R ;
Wokaun, A ;
Graubner, VM ;
Nuyken, O .
SURFACE SCIENCE, 2003, 532 :1067-1071