Optimization of microwave plasma treatment conditions on polydimethylsiloxane films for further surface functionalization

被引:10
作者
Aymes-Chodur, Caroline [1 ]
Salmi-Mani, Hanene [1 ]
Dragoe, Diana [1 ]
Aubry-Barroca, Nadine [1 ]
Buchotte, Marie [1 ]
Roger, Philippe [1 ]
机构
[1] Univ Paris Saclay, Inst Chim Mol & Mat Orsay ICMMO, CNRS, UMR 8182, F-91405 Orsay, France
关键词
PDMS; Microwave plasma; Surface functionalization; Thiol-ene polymerization; 2P CORE-LEVEL; OXYGEN-PLASMA; GRAFT-POLYMERIZATION; HYDROPHOBIC RECOVERY; SILICONE-RUBBER; PRESSURE PLASMA; FREE-ENERGY; PDMS; GLASS; IRRADIATION;
D O I
10.1016/j.eurpolymj.2021.110416
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Polydimethylsiloxane (PDMS) was surface functionalized by a 3-steps process. Firstly, the PDMS surface was activated by means of a microwave Ar/O-2 plasma treatment, that was optimized in this paper. Secondly, the activated surface reacted with mercaptosilanes and finally a thiol-ene photopolymerization of a vanillin derivative monomer was performed. The bio-based monomer was used with the aim of giving antibacterial and antifouling properties to the PDMS surface. Grafting and photopolymerization were successfully evidenced by different analytical means and especially X-Ray Photoelectron Spectroscopy.
引用
收藏
页数:12
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