Recent developments in decarboxylative C(aryl)-X bond formation from (hetero)aryl carboxylic acids

被引：21

作者：

Sharma, Ruchi ^{[1
]}

Yadav, M. Ramu ^{[1
]}

机构：

[1] Indian Inst Technol Delhi, Dept Chem, New Delhi 110016, India

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2021年 / 19卷 / 25期

关键词：

CROSS-COUPLING REACTIONS; CATALYZED C-N; ELECTRON-RICH; IPSO-NITRATION; ARYL CHLORIDES; COPPER; CYANATION; CARBON; FLUORINATION; HALOGENATION;

D O I：

10.1039/d1ob00675d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Decarboxylative coupling reactions using readily available (hetero)aryl carboxylic acids are a highly efficient approach for the formation of new C-C and C-X bonds. These decarboxylative coupling reactions eliminate CO2 as a by-product, resulting in a greener and environmentally more benign approach than conventional coupling reactions. In this review, we summarize the recent developments in ipso-decarboxylative C-X (X = O/N/halo/S/Se/P/CN) bond formations using (hetero)aryl carboxylic acids. Furthermore, we highlight the current limitations and future research opportunities of aryl-decarboxylative coupling reactions.

引用

页码：5476 / 5500

页数：25

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