Silver-Catalyzed Oxyphosphorylation of Unactivated Alkynes

被引：9
|
作者：
Liu, Binbin [1 ]
Song, Qingmin [1 ]
Liu, Zhaohong [1 ]
Wang, Zikun [1 ]
机构：
[1] Northeast Normal Univ, Dept Chem, Jilin Prov Key Lab Organ Funct Mol Design & Synth, Changchun 130024, Peoples R China
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2021年 / 363卷 / 13期
基金：
中国国家自然科学基金;
关键词：
Alkynes; Silver-catalyzed; Hydroazidation; beta-Ketophosphine oxides; Pyrroles; H-PHOSPHINE OXIDES; C-H/P-H; VINYL AZIDES; ONE-POT; TERMINAL ALKYNES; METAL-FREE; AEROBIC OXYPHOSPHORYLATION; BETA-KETOPHOSPHONATES; CHEMICAL-SYNTHESIS; FACILE SYNTHESIS;
D O I：
10.1002/adsc.202100226
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Here, we describe an application of hydroazidation in the instant activation of alkynes for achieving the oxyphosphorylation of unactivated alkynes with diarylphosphinoyl radicals under mild reaction conditions. This reaction provides a method for accessing beta-ketophosphine oxides and phosphorus-containing pyrroles.
引用
收藏
页码：3214 / 3219
页数：6
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