Microwave-Assisted Treatment of Waste Wood Biomass with Deep Eutectic Solvents (vol 404, 2100284, 2022)

被引:0
作者
Colella, Marco
Romanazzi, Giuseppe
Petrelli, Valentina
Baldassarre, Francesca
Ciccarella, Giuseppe
Catauro, Michelina
Mastrorilli, Piero
Dell'Anna, Maria Michela
机构
[1] Politecnico di Bari, DICATECh, via Orabona, 4, Bari
[2] Dipartimento di Scienze e Tecnologie Biologiche ed Ambientali & UdR INSTM, Università del Salento, via Monteroni, Lecce
[3] Istituto di Nanotecnologia − CNR NANOTEC, Consiglio Nazionale delle Ricerche, Via Monteroni, Lecce
[4] Dipartimento di Ingegneria, Università degli Studi della Campania, via Roma 29, Aversa
关键词
biorefinery; deep eutectic solvents; lignocellulose treatment; microwave; wood biomass;
D O I
10.1002/masy.202270021
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Deep eutectic solvents (DESs) are new sustainable and cheap reaction media combining the features of both ionic liquids and organic solvents. They are made up by association of hydrogen-bond donors and hydrogen-bond acceptors, and they can promote the hydrolysis of lignocellulosic bonds. Herein the microwave-assisted treatment of waste wood flours with a DES constituted by choline chloride and oxalic acid to get a cellulosic residue separated from lignin degradation products is reported. The insoluble deposit is characterized by SEM, TGA, DSC, FTIR-ATR, and 1H-13C CP/MAS NMR techniques and can be available for further uses such as nanocellulose production. © 2022 Wiley-VCH GmbH.
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[1]  
Colella M, 2022, MACROMOL SYMP, V404, DOI 10.1002/masy.202100284