A multi-walled carbon nanotube/poly(urea-formaldehyde) composite prepared by in situ polycondensation for enhanced electrochemical sensing

被引：20
作者：
Wei, Bangguo [1 ]
Zhang, Luyan [1 ]
Chen, Gang [1 ]
机构：
[1] Fudan Univ, Dept Chem, Sch Pharm, Shanghai 200433, Peoples R China
来源：
NEW JOURNAL OF CHEMISTRY | 2010年 / 34卷 / 03期
关键词：
UREA-FORMALDEHYDE RESINS; NANOTUBE-MODIFIED ELECTRODES; CAPILLARY-ELECTROPHORESIS; GLASSY-CARBON; BIOSENSORS; POLYMERIZATION; DETECTORS; GRAPHITE; SYSTEM;
D O I：
10.1039/b9nj00670b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel multi-walled carbon nanotube/poly(urea-formaldehyde) (CNT/PUF) composite was prepared for enhanced electrochemical sensing. The composite electrodes were fabricated by the in situ polycondensation of a mixture containing CNTs, and the urea and formaldehyde prepolymer, in electrode tubes with the aid of a curing catalyst. The morphology and structure of the novel composite were investigated by scanning electron microscopy, X-ray diffraction and Fourier transform infrared spectroscopy. The results indicate that the CNTs were well dispersed and embedded throughout the PUF matrix to form an interconnected CNT network. The electrocatalytic performance of the CNT/PUF composite electrodes was demonstrated by measuring phenols using cyclic voltammetry and microchip capillary electrophoresis.
引用
收藏
页码：453 / 457
页数：5
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