Enhanced tunneling electroresistance effects in HfZrO-based ferroelectric tunnel junctions by high-pressure nitrogen annealing

被引:59
作者
Goh, Youngin [1 ]
Jeon, Sanghun [2 ]
机构
[1] Korea Univ, Dept Appl Phys, 2511 Sejongro, Sejong 339700, South Korea
[2] Korea Adv Inst Sci & Technol, Sch Elect Engn, 291 Daehakro, Daejeon 34141, South Korea
关键词
FILMS;
D O I
10.1063/1.5040031
中图分类号
O59 [应用物理学];
学科分类号
摘要
Greatly improved ferroelectricity with an excellent remanent polarization of 20 mu C/cm(2) and enhanced tunneling electroresistance (TER) were achieved with TiN/HtZrO(HZO)/p-type Ge ferroelectric tunnel junctions (FTJs) annealed at a high pressure of 200 atmosphere (atm.). We found that the enhanced ferroelectric characteristics can be ascribed to the effective formation of an orthorhombic phase at high pressures. This was verified by the combined study of grazing angle incidence X-ray diffraction, transmission electron microscopy, and hysteresis polarization curve analyses. in addition, using pulse switching measurements, we quantitatively evaluated the interfacial paraelectric capacitance (C-i) of HZO FTJs according to the annealing temperature. HZO films annealed at 550 degrees C and 200 atm, exhibited an excellent TER effect ratio of 20 due to the extra paraelectric layer between the ferroelectric layer and the bottom electrode and a relatively high remanent polarization. Published by AIP Publishing.
引用
收藏
页数:5
相关论文
共 25 条
[21]   Overcoming the Fundamental Barrier Thickness Limits of Ferroelectric Tunnel Junctions through BaTiO3/SrTiO3 Composite Barriers [J].
Wang, Lingfei ;
Cho, Myung Rae ;
Shin, Yeong Jae ;
Kim, Jeong Rae ;
Das, Saikat ;
Yoon, Jong-Gul ;
Chung, Jin-Seok ;
Noh, Tae Won .
NANO LETTERS, 2016, 16 (06) :3911-3918
[22]   Nanoionics-based resistive switching memories [J].
Waser, RaineR ;
Aono, Masakazu .
NATURE MATERIALS, 2007, 6 (11) :833-840
[23]  
Wen Z, 2013, NAT MATER, V12, P617, DOI [10.1038/NMAT3649, 10.1038/nmat3649]
[24]   Flexible Inorganic Ferroelectric Thin Films for Nonvolatile Memory Devices [J].
Yu, Hyeonggeun ;
Chung, Ching-Chang ;
Shewmon, Nate ;
Ho, Szuheng ;
Carpenter, Joshua H. ;
Larrabee, Ryan ;
Sun, Tianlei ;
Jones, Jacob L. ;
Ade, Harald ;
O'Connor, Brendan T. ;
So, Franky .
ADVANCED FUNCTIONAL MATERIALS, 2017, 27 (21)
[25]   Giant electroresistance in ferroelectric tunnel junctions [J].
Zhuravlev, MY ;
Sabirianov, RF ;
Jaswal, SS ;
Tsymbal, EY .
PHYSICAL REVIEW LETTERS, 2005, 94 (24)