Cobalt-catalysed transfer hydrogenation of quinolines and related heterocycles using formic acid under mild conditions

被引：45

作者：

Cabrero-Antonino, Jose R. ^{[1
]}

Adam, Rosa ^{[1
]}

Junge, Kathrin ^{[1
]}

Jackstell, Ralf ^{[1
]}

Beller, Matthias ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29a, D-18059 Rostock, Germany

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2017年 / 7卷 / 10期

关键词：

ASYMMETRIC TRANSFER HYDROGENATION; N-HETEROCYCLES; STORAGE MATERIAL; WATER; DEHYDROGENATION; EFFICIENT; KETONES; HETEROARENES; COMPLEXES; NITRILES;

D O I：

10.1039/c7cy00437k

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Herein, we report the first example of homogeneous non-noble metal-catalyzed transfer hydrogenation of N-heteroarenes. The combination of Co(BF4)(2)center dot 6H(2)O with tris.2-(diphenylphosphino)phenyl)phosphine L1 is able to selectively reduce quinolines in the presence of other sensitive functional groups, under mild conditions, using formic acid as a hydrogen source.

引用

收藏

页码：1981 / 1985

页数：5

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