Deactivation of light naphtha aromatization catalyst

被引:0
|
作者
Fukase, S [1 ]
Igarashi, N [1 ]
Aimoto, K [1 ]
Kato, K [1 ]
机构
[1] JAPAN ENERGY CORP,PETR REFINING DEPT,MINATO KU,TOKYO 105,JAPAN
来源
DEACTIVATION AND TESTING OF HYDROCARBON-PROCESSING CATALYSTS | 1996年 / 634卷
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Deactivation of light naphtha aromatization catalyst based on zeolite was studied, by kinetic analysis, micropore volume analysis and model reactions. Coke accumulates at the entrance of zeolite channel, blocks it and hinders reactant molecule to access active sites in zeolite channel. Our own stabilization technique passivates coke-forming sites at the external surface of the zeolite. This minimizes the coke formation at the entrance of zeolite channel and increases on-stream stability. The stabilized catalyst enabled us to develop a new light naphtha aromatization process using an idle heavy naphtha reformer that is replaced by CCR process.
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页码:219 / 228
页数:10
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