A multicarboxyl antiscalant for calcium phosphate and calcium carbonate deposits in cooling water systems

被引:10
|
作者
Cao, Ke [1 ]
Huang, Jingyi [1 ]
Zhou, Yuming [1 ]
Liu, Guangqing [1 ,3 ]
Wang, Huchuan [1 ]
Yao, Qingzhao [1 ]
Liu, Yahui [1 ]
Sun, Wei [2 ]
Wu, Wendao [2 ]
机构
[1] Southeast Univ, Sch Chem & Chem Engn, Nanjing 211189, Jiangsu, Peoples R China
[2] Jianghai Environm Protect Co Ltd, Changzhou 213116, Jiangsu, Peoples R China
[3] Nanjing Xiaozhuang Univ, Sch Biochem & Environm Engn, Nanjing 211189, Jiangsu, Peoples R China
基金
中国国家自然科学基金;
关键词
Antiscalant; Calcium phosphate; Phosphorous free; Copolymer; Calcium carbonate; SCALE INHIBITION; HIGH-TEMPERATURE; GROWTH;
D O I
10.1080/19443994.2013.825882
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
A "green" antiscalant of acrylic acid-allylpolyethoxy carboxylate (AA-APEY or AY) was prepared by copolymerization of allylpolyethoxy carboxylate and acrylic acid at different mole ratios. The effect of different AA-to-APEY mole ratios on controlling calcium deposits was studied, and their performance was compared with current commercial inhibitors. It was shown that AY exhibited excellent ability to control inorganic minerals, with approximately 100% calcium phosphate inhibition and 80% calcium carbonate inhibition at dosage of 8 and 6 mg/L, respectively. The micromorphology and crystal of calcium particles were characterized by scanning electron microscopy and X-ray diffraction.
引用
收藏
页码:7258 / 7264
页数:7
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