Nanostructured ZnO: from monodisperse nanoparticles to nanorods

被引:74
作者
Ge, M. Y.
Wu, H. P.
Niu, L.
Liu, J. F.
Chen, S. Y.
Shen, P. Y.
Zeng, Y. W.
Wang, Y. W.
Zhang, G. Q.
Jiang, J. Z. [1 ]
机构
[1] Zhejiang Univ, Dept Mat Sci & Engn, Lab New Struct Mat, Hangzhou 310027, Peoples R China
[2] I Shou Univ, Dept Mech Engn, Kaohsiung, Taiwan
[3] Natl Sun Yat Sen Univ, Inst Mat Sci & Engn, Kaohsiung 80424, Taiwan
[4] Zhejiang Univ, Anal & Testing Ctr, Hangzhou 310027, Peoples R China
[5] Zhejiang Sci Tech Univ, Ctr Anal, Hangzhou 310018, Peoples R China
基金
中国国家自然科学基金;
关键词
nanomaterials; semiconducting II-VI materials; zinc oxide;
D O I
10.1016/j.jcrysgro.2007.03.016
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
A simple method was used to prepare monodispersed ZnO nanoparticles, which can be used as seeds for the synthesis of [0 0 0 1]oriented ZnO nanorods by refluxing. Based on the observation of shape and size of ZnO nanocrystals at different refluxing times and surface and attachment energies for various crystallographic planes calculated from the BFDH and HP models, a possible growth mechanism for ZnO nanorods was put forward to explain the experimental observations. The synthesized ZnO nanocrystals show green emission, which are correlated with the degree of oxygen vacancies in the samples. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:162 / 166
页数:5
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