A novel functionalized P,C,P pincer ligand complex

被引：30
作者：
Grimm, JC
Nachtigal, C
Mack, HG
Kaska, WC
Mayer, HA
机构：
[1] Univ Tubingen, Inst Anorgan Chem, D-72076 Tubingen, Germany
[2] Univ Tubingen, Inst Theoret & Phys Chem, D-72076 Tubingen, Germany
[3] Univ Calif Santa Barbara, Dept Chem, Santa Barbara, CA 93106 USA
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2000年 / 3卷 / 10期
关键词：
pincer ligands; iridium complexes; X-ray structure; quantum chemical calculations;
D O I：
10.1016/S1387-7003(00)00132-5
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reaction of 3,5-di(bromomethyl)nitrobenzene with di-t-butylphosphine and subsequent treatment with sodium acetate gives the novel functionalized P,C,P pincer ligand 2. Heating an isopropanol/water solution of 2 with iridium(LII)chloride results in the iridium hydrochloride complex 3. This complex was characterized by X-ray structure analysis in the solid state, NMR spectroscopy in solution, and density functional calculations in the gas phase. (C) 2000 Elsevier Science S.A. All rights reserved.
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收藏
页码：511 / 514
页数：4
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