Luminescence properties of novel yellowish-green-emitting phosphor KBaBP2O8:Tb3+

被引:15
作者
Han, Bing [1 ]
Zhang, Jie [1 ]
Li, Pengju [1 ]
Shi, Hengzhen [1 ]
机构
[1] Zhengzhou Univ Light Ind, Sch Mat & Chem Engn, Zhengzhou 450002, Peoples R China
来源
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE | 2014年 / 211卷 / 11期
基金
中国国家自然科学基金;
关键词
doping; KBaBP2O8; luminescence; phosphors; terbium; PHOTOLUMINESCENCE PROPERTIES; ENERGY-TRANSFER; WHITE LEDS; TB3+; LI+; DISPLAYS; EMISSION; FIELD; HOST;
D O I
10.1002/pssa.201431204
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A series of novel yellowish-green-emitting K1+xBa1-2xTbxBP2O8 (0.02x0.15) phosphors were first synthesized by a high-temperature solid-state reaction method, and their phase purity as well as photoluminescence properties were investigated by X-ray diffraction (XRD) and fluorescence spectroscopy (FS) measurements, respectively. The influence of the doping concentration of Tb3+ on its relative emission intensity and decay behavior was systematically investigated. The critical distance as well as the concentration-quenching mechanism was calculated and confirmed. The as-prepared phosphor can be excited effectively with a 370nm light, and exhibit yellowish-green emission with a short decay time of the order of millisecond. The above work indicates this phosphor could be a potential candidate as a yellowish-green-emitting phosphor for application in white-light-emitting diodes.
引用
收藏
页码:2483 / 2487
页数:5
相关论文
共 27 条
[1]  
BLASSE G, 1969, PHILIPS RES REP, V24, P131
[2]   Luminescent properties of novel K3R(PO4)2:Tb3+ (R=Y and Gd) phosphors for displays and lightings [J].
Chen, Si ;
Wang, Yuhua ;
Zhang, Jia ;
Zhao, Lei ;
Wang, Qian ;
Han, Lili .
JOURNAL OF LUMINESCENCE, 2014, 150 :46-49
[3]  
Chen X., 2014, J. Solid State Light, V1, P4, DOI [10.1186/2196-1107-1-4, DOI 10.1186/2196-1107-1-4]
[4]  
Dieke G.H., 1968, Spectra and energy levels OF rare earth IONS IN crystals
[5]   Synthesis and photoluminescence properties of a new green emitting phosphor La2SrB10O19:Tb3+ [J].
Guo, Rui ;
Tang, Songling ;
Cheng, Baochang ;
Tan, Dunqiang ;
Xiong, Yuhua .
OPTICAL MATERIALS, 2013, 35 (08) :1609-1611
[6]   Green emission of Ca3La3(1-x)Tb3x(BO3)5 under VUV-UV excitation [J].
Han, B. ;
Liang, H. B. ;
Lin, H. H. ;
Zhong, J. P. ;
Su, Q. ;
Zhang, G. B. ;
Fu, Y. B. .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2007, 88 (04) :705-709
[7]   Observation of efficient energy transfer from host to rare-earth ions in KBaY(BO3)2:Tb3+ phosphor for plasma display panel [J].
Han, Lili ;
Wang, Yuhua ;
Wang, Yanzhao ;
Zhang, Jia ;
Tao, Ye .
JOURNAL OF ALLOYS AND COMPOUNDS, 2013, 551 :485-489
[8]   Recent Developments in the Field of Inorganic Phosphors [J].
Hoeppe, Henning A. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (20) :3572-3582
[9]   Structure and photoluminescence properties of novel Ca2NaSiO4F:Re (Re = Eu2+, Ce3+, Tb3+) phosphors with energy transfer for white emitting LEDs [J].
Jiao, Mengmeng ;
Jia, Yongchao ;
Lu, Wei ;
Lv, Wenzhen ;
Zhao, Qi ;
Shao, Baiqi ;
You, Hongpeng .
JOURNAL OF MATERIALS CHEMISTRY C, 2014, 2 (21) :4304-4311
[10]   Luminescent characteristics of LiBaBO3:Tb3+ green phosphor for white LED [J].
Li, Panlai ;
Pang, Libin ;
Wang, Zhijun ;
Yang, Zhiping ;
Guo, Qinglin ;
Li, Xu .
JOURNAL OF ALLOYS AND COMPOUNDS, 2009, 478 (1-2) :813-815