Chromium(VI) distributions in the Arctic and the Atlantic Oceans and a reassessment of the oceanic Cr cycle

被引:40
作者
Sirinawin, W
Turner, DR [1 ]
Westerlund, S
机构
[1] Univ Gothenburg, SE-41296 Gothenburg, Sweden
[2] Rogaland Res, N-4004 Stavanger, Norway
关键词
chromium; chromium(VI); Arctic Ocean; Atlantic Ocean; seawater;
D O I
10.1016/S0304-4203(00)00055-4
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Chromium(VI) concentrations ranging between 3.0 and 6.1 nmol l(-1) and 3.1 and 7.3 nmol l(-1) were found in the Arctic and Atlantic Oceans, respectively. The vertical profiles show modest depletion of chromium(VI) in surface waters, but poor overall correlations between Cr(VI) and nutrient profiles. Given that Cr(VI) is the dominant oxidation state of chromium in open-ocean waters, these data are combined with literature data to reassess the distribution of Cr in oceanic waters. It is concluded that while Cr shows some characteristics of both "recycled" and "accumulated" vertical profiles, it does not fall clearly within either group. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:265 / 282
页数:18
相关论文
共 33 条
[1]   The distribution of dissolved Cu, Zn, Ni, Co and Cr in English coastal surface waters [J].
Achterberg, EP ;
Colombo, C ;
van den Berg, CMG .
CONTINENTAL SHELF RESEARCH, 1999, 19 (04) :537-558
[2]   Chemical speciation of chromium and nickel in the western Mediterranean [J].
Achterberg, EP ;
van den Berg, CMG .
DEEP-SEA RESEARCH PART II-TOPICAL STUDIES IN OCEANOGRAPHY, 1997, 44 (3-4) :693-720
[3]  
Alloway B., 1997, Chemical Principles of Environmental Pollution
[4]   WATER MASSES AND CIRCULATION IN THE EURASIAN BASIN - RESULTS FROM THE ODEN 91 EXPEDITION [J].
ANDERSON, LG ;
BJORK, G ;
HOLBY, O ;
JONES, EP ;
KATTNER, G ;
KOLTERMANN, KP ;
LILJEBLAD, B ;
LINDEGREN, R ;
RUDELS, B ;
SWIFT, J .
JOURNAL OF GEOPHYSICAL RESEARCH-OCEANS, 1994, 99 (C2) :3273-3283
[5]   THE DETERMINATION OF THE CHROMIUM SPECIATION IN SEA-WATER USING CATALYTIC CATHODIC STRIPPING VOLTAMMETRY [J].
BOUSSEMART, M ;
VAN DEN BERG, CMG ;
GHADDAF, M .
ANALYTICA CHIMICA ACTA, 1992, 262 (01) :103-115
[6]   DISSOLVED CHROMIUM IN THE NORTHWEST ATLANTIC-OCEAN [J].
CAMPBELL, JA ;
YEATS, PA .
EARTH AND PLANETARY SCIENCE LETTERS, 1981, 53 (03) :427-433
[7]   DISSOLVED CHROMIUM IN THE ST-LAWRENCE ESTUARY [J].
CAMPBELL, JA ;
YEATS, PA .
ESTUARINE COASTAL AND SHELF SCIENCE, 1984, 19 (05) :513-522
[8]   CHROMIUM IN CASCADIA BASIN, NORTHEAST PACIFIC-OCEAN [J].
CRANSTON, RE .
MARINE CHEMISTRY, 1983, 13 (02) :109-125
[9]   DETERMINATION OF CHROMIUM SPECIES IN NATURAL-WATERS [J].
CRANSTON, RE ;
MURRAY, JW .
ANALYTICA CHIMICA ACTA, 1978, 99 (02) :275-282
[10]   Metalloids in the high latitude north Atlantic Ocean: Sources and internal cycling [J].
Cutter, GA ;
Cutter, LS .
MARINE CHEMISTRY, 1998, 61 (1-2) :25-36