Enantioselective copper(I) catalyzed 1,4-addition of diethylzinc to nitroolefins

被引:86
作者
Sewald, N [1 ]
Wendisch, V [1 ]
机构
[1] Univ Leipzig, Dept Organ Chem, D-04103 Leipzig, Germany
关键词
D O I
10.1016/S0957-4166(98)00125-6
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The asymmetric 1,4-addition of diethylzinc to nitroolefins is efficiently catalyzed by copper(I) complexes with BINOL based phosphoramidite ligands. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
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页码:1341 / 1344
页数:4
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共 41 条
[11]  
DEVRIES AHM, 1996, ANGEW CHEM, V108, P2526
[12]   Highly enantioselective catalytic conjugate addition and tandem conjugate addition - Aldol reactions of organozinc reagents [J].
Feringa, BL ;
Pineschi, M ;
Arnold, LA ;
Imbos, R ;
de Vries, AHM .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1997, 36 (23) :2620-2623
[13]  
FERINGA BL, 1997, ANGEW CHEM, V109, P2733
[14]   Synthesis of a beta-hexapeptide from (R)-2-aminomethyl-alkanoic acids and structural investigations [J].
Hintermann, T ;
Seebach, D .
SYNLETT, 1997, (05) :437-&
[15]   CATALYTIC ENANTIOSELECTIVE CONJUGATE ADDITION OF DIETHYLZINC USING NI(II) DAIB COMPLEXES [J].
JANSEN, JFGA ;
FERINGA, BL .
TETRAHEDRON-ASYMMETRY, 1992, 3 (05) :581-582
[16]  
KABBARA J, 1994, SYNLETT, P679
[17]  
Knobel AKH, 1997, SYNLETT, P1429
[18]   PREPARATION AND REACTIONS OF POLYFUNCTIONAL ORGANOZINC REAGENTS IN ORGANIC-SYNTHESIS [J].
KNOCHEL, P ;
SINGER, RD .
CHEMICAL REVIEWS, 1993, 93 (06) :2117-2188
[19]  
KNOCHEL P, 1982, SYNTHESIS-STUTTGART, P1017
[20]  
Kozlowski J. A, 1991, COMPREHENSIVE ORGANI, V4, P169