Strategic developments in living anionic polymerization of alkyl (meth)acrylates

被引：149
|
作者：
Baskaran, D [1 ]
机构：
[1] Natl Chem Lab, Div Polymer Chem, Pune 411008, Maharashtra, India
来源：
PROGRESS IN POLYMER SCIENCE | 2003年 / 28卷 / 04期
关键词：
anionic polymerization; group transfer polymerization; metal-free anionic polymerization; ligated anionic polymerization; alkyl (meth)acrylates; ligands; additives;
D O I：
10.1016/S0079-6700(02)00083-7
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Controlling living anionic polymerization of alkyl (meth)acrylate is complicated due to side reactions associated with ester functionality as well as the presence of aggregated enolate active centers. In the last two decades, several research groups have identified new strategies to circumvent the problem of termination and aggregation in the alkyl (meth)acrylate polymerization. This paper reviews the past and recent developments in living anionic polymerization of alkyl (meth)acrylates using different initiating systems and in the presence of various additives/ligands in conjunction with classical anionic initiator. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：521 / 581
页数：61
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