Catalytic conversion of furfural-acetone condensation products into bio-derived C8 linear alcohols over Ni-Cu/Al-SBA-15

被引：12

作者：

Ramos, Ruben ^{[1
]}

Hidalgo, Jose M. ^{[1
]}

Gonel, Michael ^{[1
]}

Tiser, Zdenek ^{[1
]}

Bertella, Francine ^{[2
]}

Martinez, Agustin ^{[2
]}

Kikhtyanin, Oleg ^{[1
,3
]}

Kubicka, David ^{[3
]}

机构：

[1] Unipetrol Ctr Res & Educ UNICRE, Zaluzi Litvinov 43670, Czech Republic

[2] Univ Politecn Valencia, CSIC, Inst Tecnol Quim, Avda Naranjos S-N, E-46022 Valencia, Spain

[3] Univ Chem & Technol Prague, Technopk Kralupy, Zizkova 7, Kralupy Nad Vltavou 27801, Czech Republic

来源：

CATALYSIS COMMUNICATIONS | 2018年 / 114卷

关键词：

Furfural; Aldol condensation; Hydrogenation; SBA-15; Ni-Cu catalysts; DROP-IN BIOFUELS; ALDOL CONDENSATION; SELECTIVE CONVERSION; SUPPORTED CATALYSTS; HYDROGEN-PRODUCTION; MILD CONDITIONS; MIXED OXIDES; HYDRODEOXYGENATION; ALKANES; ACID;

D O I：

10.1016/j.catcom.2018.06.006

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The production of C-8 linear diols from a furfural-acetone condensation product has been achieved for the first time using a non-noble metal based catalyst. In particular, SBA-15 supported Ni-Cu bimetallic catalyst showed the best hydrogenating activity reaching an outstanding yield (ca. 63%) of the fully saturated product. The incorporation of acidity by the preparation of Ni-Cu/Al-SBA-15 resulted in the promotion of ring-opening steps, which led to a remarkable yield of C-8 linear diols (28%). These results establish a competitive catalytic route for the production of bio-based diols over cost-efficient 3d transition metal-based catalysts.

引用

页码：42 / 45

页数：4

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