Formation of radical cations of aziridines generated by laser ash photolysis

被引:3
|
作者
Gaebert, C
Siegner, C
Mattay, J
Toubartz, M
Steenken, S
机构
[1] Univ Bielefeld, D-33615 Bielefeld, Germany
[2] Max Planck Inst Bioanorgan Chem, D-45470 Mulheim, Germany
[3] Consortium Elektrochem Ind GmbH, D-81379 Munich, Germany
[4] Plaut Consulting, D-69126 Heidelberg, Germany
关键词
D O I
10.1039/b410464a
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The radical cations of 1-butyl-trans-2,3-diphenyl aziridine (1), 1-butyl-2-phenyl aziridine (2), 1,2-diphenyl aziridine (3) and 1-(p-methoxyphenyl)-2-phenyl aziridine (4) were generated upon laser flash photolysis in aqueous and aqueous acetonitrile solutions by direct photoionisation as indicated by the broad absorption band of the solvated electron above 550 nm as well.
引用
收藏
页码:990 / 991
页数:2
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