Iminopinacol coupling with lithium: electron-transfer mediators

被引：3

作者：

Mistryukov, EA ^{[1
]}

机构：

[1] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 119991, Russia

来源：

MENDELEEV COMMUNICATIONS | 2002年 / 06期

关键词：

D O I：

10.1070/MC2002v012n06ABEH001617

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The addition of tert-butyl borate or ethyl formate to N-alkylbenzalimines directs the reaction pathway from the Birch reduction to the pinacol-type coupling with lithium in THF; an analogous reaction with a dimethylimmonium salt requires a trace titanium catalyst as the electron-transfer mediator.

引用

页码：230 / 231

页数：2

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