Partial oxidation of methane over bimetallic nickel-lanthanide oxides

被引:37
作者
Ferreira, Ana C. [1 ]
Ferraria, A. M. [2 ]
Botelho do Rego, A. M. [2 ]
Goncalves, Antonio P. [1 ]
Correia, M. Rosario [3 ]
Gasche, T. Almeida [1 ]
Branco, Joaquim B. [1 ]
机构
[1] Inst Tecnol & Nucl, Unidade Ciencias Quim & Radiofarmaceut, P-2686953 Sacavem, Portugal
[2] Univ Tecn Lisboa, IST, Ctr Quim Fis Mol & IN, P-1049001 Lisbon, Portugal
[3] Univ Aveiro, I3N, Dept Fis, P-3810193 Aveiro, Portugal
关键词
Intermetallic; Bimetallic nickel-lanthanide oxides; Methane; Partial oxidation; CATALYTIC PARTIAL OXIDATION; TEMPERATURE-PROGRAMMED REDUCTION; NI-BASED CATALYSTS; SYNTHESIS GAS; SELECTIVE OXIDATION; CARBON-MONOXIDE; METAL; PERFORMANCE; CONVERSION; SYNGAS;
D O I
10.1016/j.jallcom.2009.09.082
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The study of partial oxidation of methane (POM) over bimetallic nickel-lanthanide oxides was undertaken. Binary intermetallic compounds of the type LnNi (Ln = Pr, Gd, Lu) were used as bimetallic nickel-lanthanide oxides precursors and the products (NiO center dot Pr2NiO4, 2NiO center dot Gd2O3 and 2NiO center dot Lu2O3) were characterized by means of X-ray diffraction, X-ray photoelectron spectroscopy, Raman and temperature programmed reduction. The catalytic activity increases when gadolinium or lutetium replaces praseodymium and the selectivity of the bimetallic nickel-lanthanide oxides is clearly different from that of single metal oxides and/or mechanical mixtures. The existence of an unusual synergism effect between the two metal oxide phases (NiO and Ln(2)O(3)) that lead to higher conversions of methane and higher selectivities to hydrogen and carbon monoxide correlate also the catalysts stability to deactivation. The activity and selectivity of the gadolinium and lutetium compounds is, under the same conditions, equivalent to that of a platinum commercial catalyst, 5wt% Pt/Al2O3, which stresses the good catalytic performance of this new type of compounds for the production of H-2 and CO (H-2/CO = 2). (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:316 / 323
页数:8
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