ICP-MS determination of Pt, Pd and Rh in airborne and road dust after tellurium coprecipitation

被引：93

作者：

Gómez, MB ^{[1
]}

Gómez, MM ^{[1
]}

Palacios, MA ^{[1
]}

机构：

[1] Univ Complutense Madrid, Fac CC Quim, Dept Quim Analit, E-28040 Madrid, Spain

来源：

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY | 2003年 / 18卷 / 01期

关键词：

D O I：

10.1039/b209727n

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A method has been developed for the simultaneous determination of Pd, Pt and Rh (PGE) in environmental airborne and road dust samples by tellurium coprecipitation and ICP-MS. The Te coprecipitation was applied after digestion of the sample with aqua regia-HF in a microwave oven. This separation method removes more than 95% of the elements producing mass interference in PGE determination by ICP-MS. The methodology was validated with reference road dust samples CW7 and CW8. The detection limits are 0.3, 0.6 and 0.8 pg m(-3) for Pt, Pd and Rh in airborne particulate matter, and 1, 1 and 0.4 ng g(-1) for Pt, Pd and Rh in road dust. Application of the isotopic dilution method for Pt and Pd after their coprecipitation improves the results obtained for road dust samples. Rh (monoisotopic element) analysis was carried out by external calibration after Te coprecipitation.

引用

页码：80 / 83

页数：4

共 27 条

[1] Determination of platinum-group elements and gold in geological matrices by inductively coupled plasma-mass spectrometry (ICP-MS) after separation with selenium and tellurium carriers [J].

Amosse, J .

GEOSTANDARDS NEWSLETTER-THE JOURNAL OF GEOSTANDARDS AND GEOANALYSIS, 1998, 22 (01) :93-102

[2]

[Anonymous], 1988, INORGANIC MASS SPECT

[3] Determination of physiological palladium, platinum, iridium and gold levels in human blood using double focusing magnetic sector field inductively coupled plasma mass spectrometry [J].

Begerow, J ;

Turfeld, M ;

Dunemann, L .

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 1997, 12 (09) :1095-1098

[4]

Bunger J, 1996, INT ARCH OCC ENV HEA, V69, P33

[5]

*CEPLACA, 2001, ENV4CT970518 CEPLACA

[6] DETERMINATION OF PLATINUM, PALLADIUM, RUTHENIUM AND IRIDIUM IN GEOLOGICAL SAMPLES BY ISOTOPE-DILUTION INDUCTIVELY-COUPLED PLASMA-MASS SPECTROMETRY USING A SODIUM PEROXIDE FUSION AND TELLURIUM COPRECIPITATION [J].

ENZWEILER, J ;

POTTS, PJ ;

JARVIS, KE .

ANALYST, 1995, 120 (05) :1391-1396

[7]

*EURACHEM, 1995, QUANT UNC AN MEAS

[8]

Farago ME, 1996, FRESEN J ANAL CHEM, V354, P660

[9]

GARCIAALONSO JI, 1995, ANAL CHIM ACTA, V312, P57

[10] Levels and risk assessment for humans and ecosystems of platinum-group elements in the airborne particles and road dust of some European cities [J].

Gómez, B ;

Palacios, MA ;

Gómez, M ;

Sanchez, JL ;

Morrison, G ;

Rauch, S ;

McLeod, C ;

Ma, R ;

Caroli, S ;

Alimonti, A ;

Petrucci, F ;

Bocca, B ;

Schramel, P ;

Zischka, M ;

Petterson, C ;

Wass, U .

SCIENCE OF THE TOTAL ENVIRONMENT, 2002, 299 (1-3) :1-19

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