Room temperature NO2 sensor based on highly ordered porphyrin nanotubes

被引：17
作者：
Song, Feifei [1 ]
Ma, Pan [1 ,2 ]
Chen, Changlong [1 ]
Jia, Jingna [1 ]
Wang, Yucheng [1 ]
Zhu, Peihua [1 ]
机构：
[1] Univ Jinan, Shandong Univ, Sch Chem & Chem Engn, Key Lab Chem Sensing & Anal, Jinan 250022, Peoples R China
[2] Jinan Acad Agr Sci, Jinan 250316, Peoples R China
来源：
JOURNAL OF COLLOID AND INTERFACE SCIENCE | 2016年 / 474卷
关键词：
Porphyrin; Nanotube; NO2; sensor; PHTHALOCYANINE; NANOSTRUCTURES;
D O I：
10.1016/j.jcis.2016.04.012
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Highly ordered nanotubes of 5, 10, 15, 20-tetrakis(4-aminophenyl)porphyrin zinc (ZnTAP) are fabricated by using nanoporous anodized aluminum oxide (AAO) membrane as the template. Electronic absorption spectra, fluorescence spectra, transmission electron microscope (TEM), scanning electronic microscopy (SEM), low-angle X-ray diffraction (XRD) techniques are adopted to characterize these nanotubes. The highly ordered nanotubes of ZnTAP show good conductivity and present an efficient gas sensor platform for the ultrasensitive detection of NO2 under room temperature. The proposed sensor shows high sensitivity, reproducibility and fast response/recovery behavior, and provides a promising avenue for improving the sensing performance. (C) 2016 Elsevier Inc. All rights reserved.
引用
收藏
页码：51 / 57
页数：7
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