Thermolysis of 1,1-dimesityl-3-phenyl-2-trimethylsilyl-1-silacyclopropene: silylene transfer reactions to 1,4-bis(silyl)butadiynes

被引：10

作者：

Kunai, A

Mihara, T

Matsuo, Y

Ohshita, J

Naka, A

Ishikawa, M

机构：

[1] Kurashiki Univ Sci & Arts, Dept Chem Technol, Kurashiki 712, Okayama, Japan

[2] Hiroshima Univ, Fac Engn, Dept Appl Chem, Higashihiroshima 739, Japan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1997年 / 545卷

基金：

日本学术振兴会;

关键词：

thermolysis; silylene; silacyclopropene;

D O I：

10.1016/S0022-328X(97)00355-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The cothermolysis of 1,1-dimesityl-3-phenyl-2-trimethylsilyl-1-silacyclopropene (1) with 1,4-bis(trimethylsilyl)- and 1,4-bis(triethylsilyl)butadiyne at 250 degrees C for 24 h afforded 1,1-dimesityl-3-silyl-2-silylethynyl-1-silacyclopropenes (3 and 5) and dimesitylbis(silylethynyl)silanes (4 and 6), respectively. The thermolysis of silacyclopropene 3 under the same conditions cleanly produced an isomerization product 4. (C) 1997 Elsevier Science S.A.

引用

收藏

页码：611 / 613

页数：3

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