Structure and morphology of cellulose in wheat straw

被引:251
作者
Liu, RG
Yu, H
Huang, Y [1 ]
机构
[1] Chinese Acad Sci, State Key Lab Polymer Phys & Chem, Beijing 100080, Peoples R China
[2] Chinese Acad Sci, Lab Cellulose & Lignocellulos Chem, Guangzhou 510650, Peoples R China
关键词
cellulose; crystallinity; FTIR; orientation; morphology; wheat straw;
D O I
10.1023/B:CELL.0000049346.28276.95
中图分类号
TB3 [工程材料学]; TS [轻工业、手工业、生活服务业];
学科分类号
0805 ; 080502 ; 0822 ;
摘要
The structure and morphology of cellulose extracted from wheat were studied. It was found that the extraction process is effective and hemicelluloses and lignin can be extracted completely. Cellulose in wheat straw was identified as cellulose I allomorph with low crystallinity and the crystallinity of cellulose from different parts of the wheat straw has;little difference. There was no metastable cellulose Ialpha crystalline modification found in wheat straw; only the more stable cellulose I-beta crystalline modification existed. Cellulose chains in the epidermis of wheat straw were observed with their orientation along the growth direction of wheat straw, while those in parenchyma were observed with almost no preferred orientation. There are two kinds of morphologies on the surface of wheat straw. One is the fiber structure with fibrils of about 5 mum diameter, and the other is the fiber structure with serration morphology at the edge of the fiber, with which the fibers are connected together. The diameter of the latter one is about 10 mum. The vascular bundles consist of circular rings while spiral structure cellulose backbones covered with thin cellulose film were also observed.
引用
收藏
页码:25 / 34
页数:10
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