Synthesis of CdS/m-TiO2 Mesoporous Spheres and Their Application in Photocatalytic Degradation of Rhodamine B Under Visible Light

被引:14
作者
Cui Shu [1 ,2 ]
Li Xuesong [1 ]
Li Yanjuan [1 ]
Zhao Haixin [1 ]
Wang Yuanyuan [1 ]
Li Nan [1 ]
Li Xiaotian [1 ]
Li Guodong [3 ]
机构
[1] Jilin Univ, Coll Mat Sci & Engn, Key Lab Automobile Mat, Minist Educ, Changchun 130012, Jilin, Peoples R China
[2] Tonghua Normal Univ, Sch Phys, Tonghua 134002, Peoples R China
[3] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Jilin, Peoples R China
基金
中国国家自然科学基金;
关键词
Cadmium sulfide; Titanium dioxide; Heteroarchitecture; Mesoporous material; Photocatalysis; Visible light; TIO2 NANOTUBE ARRAYS; NANOFIBERS; CDS; HYDROGEN; DIOXIDE; H2S;
D O I
10.1007/s40242-017-6377-6
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
CdS/m-TiO2 heteroarchitecture with CdS nanocrystals loaded on mesoporous TiO2(m-TiO2) spheres was successfully synthesized via sol-gel method followed by solvothermal treatment. The material with uniform diameter of ca. 750 nm possesses regular mesoporous structure and large specific surface area of 100.5 m(2)/g. When used to photodegradate Rhodamine B(RB) under visible light, the CdS/m-TiO2 heteroarchitecture exhibits improved photo catalytic performance in comparison with pure m-TiO2 or CdS. The excellent photocatalytic activity is closely related to the facilitated separation of electron-hole pairs derived from the CdS/m-TiO2 heterojunction and mesoporous structure with high specific surface area and adequately exposed active sites.
引用
收藏
页码:436 / 441
页数:6
相关论文
共 28 条
[1]  
Bai S. L., 2011, APPL SURF SCI, P257
[2]   Bi2S3/TiO2 and CdS/TiO2 heterojunctions as an available configuration for photocatalytic degradation of organic pollutant [J].
Bessekhouad, Y ;
Robert, D ;
Weber, J .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2004, 163 (03) :569-580
[3]   In-situ preparation of N-TiO2/graphene nanocomposite and its enhanced photocatalytic hydrogen production by H2S splitting under solar light [J].
Bhirud, Ashwini P. ;
Sathaye, Shivaram D. ;
Waichal, Rupali P. ;
Ambekar, Jalindar D. ;
Park, Chan-J. ;
Kale, Bharat B. .
NANOSCALE, 2015, 7 (11) :5023-5034
[4]   Visible-Light Photocatalytic Conversion of Carbon Dioxide into Methane Using Cu2O/TiO2 Hollow Nanospheres [J].
Bi, Feng ;
Ehsan, Muhammad Fahad ;
Liu, Wei ;
He, Tao .
CHINESE JOURNAL OF CHEMISTRY, 2015, 33 (01) :112-118
[5]   Fabrication of Rutile TiO2-Sn/Anatase TiO2-N Heterostructure and Its Application in Visible-Light Photocatalysis [J].
Cao, Yongqiang ;
He, Tao ;
Chen, Yongmei ;
Cao, Yaan .
JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (08) :3627-3633
[6]   Titanium dioxide nanomaterials: Synthesis, properties, modifications, and applications [J].
Chen, Xiaobo ;
Mao, Samuel S. .
CHEMICAL REVIEWS, 2007, 107 (07) :2891-2959
[7]   A visible light active photocatalyst: Nano-composite with Fe-doped anatase TiO2 nanoparticles coupling with TiO2(B) nanobelts [J].
Cui, Lifeng ;
Huang, Feng ;
Niu, Mutong ;
Zeng, Lingwei ;
Xu, Ju ;
Wang, Yuansheng .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2010, 326 (1-2) :1-7
[8]   Facile synthesis of CdS@TiO2 core-shell nanorods with controllable shell thickness and enhanced photocatalytic activity under visible light irradiation [J].
Dong, Wenhao ;
Pan, Feng ;
Xu, Leilei ;
Zheng, Minrui ;
Sow, Chorng Haur ;
Wu, Kai ;
Xu, Guo Qin ;
Chen, Wei .
APPLIED SURFACE SCIENCE, 2015, 349 :279-286
[9]   Controlled synthesis of Ag-coated TiO2 nanofibers and their enhanced effect in photocatalytic applications [J].
Guan, Hongyu ;
Wang, Xiaohong ;
Guo, Yihang ;
Shao, Changlu ;
Zhang, Xintong ;
Liu, Yichun ;
Louh, Rong-Fuh .
APPLIED SURFACE SCIENCE, 2013, 280 :720-725
[10]   TiO2 Nanotube/CdS Hybrid Electrodes: Extraordinary Enhancement in the Inactivation of Escherichia coli [J].
Hayden, Steven C. ;
Allam, Nageh K. ;
El-Sayed, Mostafa A. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (41) :14406-14408