Superior Hydrogen Sensing Property of Porous NiO/SnO2 Nanofibers Synthesized via Carbonization

被引:33
作者
Liu, Hongcheng [1 ]
Wang, Feipeng [1 ]
Hu, Kelin [1 ]
Zhang, Bin [2 ]
He, Li [1 ]
Zhou, Qu [3 ]
机构
[1] Chongqing Univ, State Key Lab Power Transmiss Equipment & Syst Se, Chongqing 400044, Peoples R China
[2] Chongqing Univ, Analyt & Testing Ctr, Chongqing 401331, Peoples R China
[3] Southwest Univ, Coll Engn & Technol, Chongqing 400715, Peoples R China
基金
国家重点研发计划;
关键词
NiO/SnO2; nanofibers; p-n heterojunctions; porous nanostructure; H-2; sensor; HOLLOW NANOFIBERS; GAS; SENSOR; FABRICATION; NANOPARTICLES; PERFORMANCE; NANOSHEET;
D O I
10.3390/nano9091250
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this paper, the porous NiO/SnO2 nanofibers were synthesized via the electrospinning method along with the carbonization process. The characterization results show that the pristine SnO2-based nanofibers can form porous structure with different grain size by carbonization. The hydrogen gas-sensing investigations indicate that the NiO/SnO2 sensor exhibits more prominent sensing properties than those of pure SnO2 sensor devices. Such enhanced performance is mainly attributed to the porous nanostructure, which can provide large active adsorption sites for surface reaction. Moreover, the existence of p-n heterojunctions between NiO and SnO2 also plays a key role in enhancing gas-sensing performances. Finally, the H-2 sensing mechanism based on the NiO/SnO2 nanocomposite was proposed for developing high-performance gas sensor devices.
引用
收藏
页数:14
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