Metal-containing phthalocyanines substituted with one branched bulky moiety and six alkylthio groups

被引:27
作者
Bayir, ZA [1 ]
Merey, S [1 ]
Hamuryudan, E [1 ]
机构
[1] Istanbul Tech Univ, Dept Chem, TR-80626 Istanbul, Turkey
来源
MONATSHEFTE FUR CHEMIE | 2003年 / 134卷 / 07期
关键词
metal-phthalocyanines; unsymmetric;
D O I
10.1007/s00706-003-0004-6
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Unsymmetrically substituted metal-phthalocyanines composed of three hexylthio groups and one 1-chloro-3,4-dicyano-6-[2-(2-pyridylmethylamino)phenylthio]benzene moiety was prepared by cyclization of the reactants in the presence of the anhydrous metal salts Zn(CH3COO)(2), NiCl2, and CoCl2. The new unsymmetric phthalocyanines are very soluble in common organic solvents. The compounds were characterised by their elemental analyses, IR, H-1 NMR, MS and UV/Vis spectra.
引用
收藏
页码:1027 / 1031
页数:5
相关论文
共 23 条
[1]  
ALTUNTAS ZB, 1997, J PORPHYR PHTHALOCYA, V1, P349
[2]  
ALTUNTAS ZB, 1999, J CHEM RES S, P702
[3]  
ALTUNTAS ZB, 1999, J CHEM RES M, P3030
[4]  
BRAND U, 1996, CHEM BER, V129, P431
[5]   HEXAKIS(ALKYLTHIO)-SUBSTITUTED UNSYMMETRICAL PHTHALOCYANINES [J].
DABAK, S ;
GUL, A ;
BEKAROGLU, O .
CHEMISCHE BERICHTE-RECUEIL, 1994, 127 (10) :2009-2012
[6]  
de la Torre G, 2000, EUR J ORG CHEM, V2000, P2821
[7]   Synthesis of highly conjugated boron(III) subphthalocyanines [J].
delRey, B ;
Torres, T .
TETRAHEDRON LETTERS, 1997, 38 (30) :5351-5354
[8]   OCTAKIS(ALKYLTHIO)-SUBSTITUTED PHTHALOCYANINES AND THEIR INTERACTIONS WITH SILVER(I) AND PALLADIUM(II) IONS [J].
GUREK, AG ;
BEKAROGLU, O .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1994, (09) :1419-1423
[9]   Synthesis and characterization of new unsymmetrically substituted phthalocyanines [J].
Gürsoy, S ;
Bayir, ZA ;
Hamuryudan, E ;
Bekaroglu, O .
MONATSHEFTE FUR CHEMIE, 2000, 131 (03) :287-292
[10]  
HAMURYUDAN E, 1993, J CHEM RES-S, P460