Colloquium: Water's controversial glass transitions

被引：152

作者：

Amann-Winkel, Katrin ^{[1
,5
]}

Boehmer, Roland ^{[2
]}

Fujara, Franz ^{[3
]}

Gainaru, Catalin ^{[2
,6
]}

Geil, Burkhard ^{[4
]}

Loerting, Thomas ^{[1
]}

机构：

[1] Univ Innsbruck, Inst Phys Chem, A-6020 Innsbruck, Austria

[2] Tech Univ Dortmund, Fak Phys, D-44221 Dortmund, Germany

[3] Tech Univ Darmstadt, Inst Festkorperphys, D-64289 Darmstadt, Germany

[4] Univ Gottingen, Inst Phys Chem, Tammannstr 6, D-37077 Gottingen, Germany

[5] Stockholm Univ, AlbaNova Univ Ctr, Dept Phys, S-10691 Stockholm, Sweden

[6] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA

来源：

REVIEWS OF MODERN PHYSICS | 2016年 / 88卷 / 01期

基金：

奥地利科学基金会; 欧洲研究理事会;

关键词：

DENSITY AMORPHOUS ICE; SINGULARITY-FREE INTERPRETATION; BEAM-INDUCED AMORPHIZATION; SITU NEUTRON-DIFFRACTION; LIQUID-LIQUID TRANSITION; SUPERCOOLED WATER; X-RAY; STRUCTURAL-CHARACTERIZATION; DIELECTRIC-PROPERTIES; 1ST-ORDER TRANSITION;

D O I：

10.1103/RevModPhys.88.011002

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

Water is the most common and, judged from its numerous anomalous properties, the weirdest of all known liquids and the complexity of its pressure-temperature map is unsurpassed. A major obstacle on the way to a full understanding of water's structure and dynamics is the hard-to-explore territory within this map, colloquially named the no man's land. Many experiments suggest that just before stepping across its low-temperature border, amorphous ices undergo glass-to-liquid transitions while other interpretations emphasize the importance of underlying disordered (nano) crystalline states. Prospects for reconciling the conflicting views regarding the nature of water's glass transitions are discussed.

引用

页数：20

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