Colloquium: Water's controversial glass transitions

被引:143
作者
Amann-Winkel, Katrin [1 ,5 ]
Boehmer, Roland [2 ]
Fujara, Franz [3 ]
Gainaru, Catalin [2 ,6 ]
Geil, Burkhard [4 ]
Loerting, Thomas [1 ]
机构
[1] Univ Innsbruck, Inst Phys Chem, A-6020 Innsbruck, Austria
[2] Tech Univ Dortmund, Fak Phys, D-44221 Dortmund, Germany
[3] Tech Univ Darmstadt, Inst Festkorperphys, D-64289 Darmstadt, Germany
[4] Univ Gottingen, Inst Phys Chem, Tammannstr 6, D-37077 Gottingen, Germany
[5] Stockholm Univ, AlbaNova Univ Ctr, Dept Phys, S-10691 Stockholm, Sweden
[6] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA
基金
奥地利科学基金会; 欧洲研究理事会;
关键词
DENSITY AMORPHOUS ICE; SINGULARITY-FREE INTERPRETATION; BEAM-INDUCED AMORPHIZATION; SITU NEUTRON-DIFFRACTION; LIQUID-LIQUID TRANSITION; SUPERCOOLED WATER; X-RAY; STRUCTURAL-CHARACTERIZATION; DIELECTRIC-PROPERTIES; 1ST-ORDER TRANSITION;
D O I
10.1103/RevModPhys.88.011002
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Water is the most common and, judged from its numerous anomalous properties, the weirdest of all known liquids and the complexity of its pressure-temperature map is unsurpassed. A major obstacle on the way to a full understanding of water's structure and dynamics is the hard-to-explore territory within this map, colloquially named the no man's land. Many experiments suggest that just before stepping across its low-temperature border, amorphous ices undergo glass-to-liquid transitions while other interpretations emphasize the importance of underlying disordered (nano) crystalline states. Prospects for reconciling the conflicting views regarding the nature of water's glass transitions are discussed.
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页数:20
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