Carbon dots derived from cellobiose for temperature and phosalone detection

被引:13
作者
Liao, Xiufen [1 ]
Chen, Congjin [1 ,2 ]
Wang, Peiwen [1 ]
Zhou, Ruxia [1 ]
Zhao, Xilian [1 ]
Fan, Hui [1 ]
Huang, Zuqiang [1 ]
机构
[1] Guangxi Univ, Sch Chem & Chem Engn, Nanning 530004, Peoples R China
[2] Guangxi Univ, Sch Chem & Chem Engn, Guangxi Key Lab Petrochem Resource Proc & Proc In, Nanning 530004, Peoples R China
基金
中国国家自然科学基金;
关键词
Carbon dot; Cellobiose; Temperature sensing; Phosalone; QUANTUM DOTS; BETA-CYCLODEXTRINS; MECHANISM; CELLULOSE; NITROGEN; SENSOR; EMISSION; PROBE;
D O I
10.1016/j.materresbull.2022.111790
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Cellobiose, the hydrolysis product of cellulose and the dimer of glucose, was employed to synthesize carbon dots (CDs) via a simple hydrothermal method. The inducing of nitrogen can act as a "molecular glue ", more and more carbon clusters were "glued " together, which would push the hydrothermal reaction in the positive direction. Besides, the linear response of the fluorescence of N-CDs to temperature ensured its potential application in temperature sensing. In the temperature range of 10 similar to 80 degrees C, the fluorescence of as-prepared N-CDs was reversible and recoverable. Moreover, the dual fluorescence centers and dual-absorption bands of the as prepared N-CDs permitted the novel dual-mode ratiometric assays for phosalone detection. The linear range and limit of detection (LOD) for dual fluorescence center-based ratiometric assay were 0.12 similar to 5.45 mu g/mL and 42.90 ng/mL, respectively. While that for the dual absorption-based ratiometric assay were 0.02 similar to 1.40 mu g/mL, and 6.67 ng/mL, respectively.
引用
收藏
页数:9
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