Evidence of covalent bond formation at the silane-metal interface during plasma polymerization of bis-1,2-(triethoxysilyl)ethane (BTSE) on aluminium

被引：23

作者：

Batan, A. ^{[1
,2
]}

Mine, N. ^{[2
]}

Douhard, B. ^{[2
]}

Brusciotti, F. ^{[3
]}

De Graeve, I. ^{[3
]}

Vereecken, J. ^{[3
]}

Wenkin, M. ^{[4
]}

Piens, M. ^{[4
]}

Terryn, H. ^{[3
]}

Pireaux, J. J. ^{[2
]}

Reniers, F. ^{[1
]}

机构：

[1] Univ Libre Bruxelles, B-1050 Brussels, Belgium

[2] Univ Namur FUNDP, Res Ctr Phys Matter & Radiat PMR, B-5000 Namur, Belgium

[3] Vrije Univ Brussel, Res Grp Electrochem & Surface Engn SURF, Brussels, Belgium

[4] Coating Res Inst CoRI, Limelette, Belgium

来源：

CHEMICAL PHYSICS LETTERS | 2010年 / 493卷 / 1-3期

关键词：

Plasma polymer films; Silane; ToF-SIMS; BTSE; XPS; TOF-SIMS; GAMMA-GLYCIDOXYPROPYLTRIMETHOXYSILANE; FILMS; DEPOSITION;

D O I：

10.1016/j.cplett.2010.05.002

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Silane and silane-like films were deposited from bis-1,2-(triethoxysilyl) ethane by vacuum and atmospheric plasma onto aluminium. Time-of-flight secondary ion mass spectrometry (ToF-SIMS) was used for probing the aluminium/plasma polymer film interface. An AlOSi+ fragment was identified at nominal mass m/z = 70.9539 amu, indicating a strong chemical interaction (formation of a covalent bond) at the substrate/film interface. Until now, this strong silane-aluminium interaction has never been observed in plasma polymer BTSE films. Ageing tests in an ultrasonic water bath combined with X-ray photoelectron spectroscopy measurements allowed to indirectly confirm good adhesion, and therefore the formation of a chemical bond at the interface. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：107 / 112

页数：6

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