Removal of SO2 by activated carbon fibre impregnated with transition metals

被引：0

作者：

Gaur, Vivekanand ^{[1
]}

Sharma, Ashutosh ^{[1
]}

Verma, Nishith ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem Engn, Kanpur 208016, Uttar Pradesh, India

来源：

CANADIAN JOURNAL OF CHEMICAL ENGINEERING | 2007年 / 85卷 / 02期

关键词：

activated carbon fibres; catalytic oxidation; impregnation; modelling; surface areas;

D O I：

暂无

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Phenolic resin based activated carbon fibres (ACF) impregnated with oxides of various transition metals were investigated for the catalytic oxidation of SO2 into H2SO4. Oxidation was carried out in the packed bed tubular reactor in the presence of O-2 and H2O. The activity of the various metals impregnated on ACF was observed to be in the order, Cu > N > Co > Cr. It was found that the metal oxides were dispersed as monolayer on ACF up to similar to 5% (w/w) loading, beyond which crystallites formation occurred. A kinetic mechanism for the catalytic oxidation of SO2 into H2SO4 was proposed and incorporated in a transport model developed to explain the experimental breakthrough data.

引用

页码：188 / 198

页数：11

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