A significantly improved membrane for vanadium redox flow battery

被引:157
作者
Jia, Chuankun [1 ]
Liu, Jianguo [1 ]
Yan, Chuanwei [1 ]
机构
[1] Chinese Acad Sci, Inst Met Res, State Key Lab Corros & Protect, Shenyang 110016, Peoples R China
关键词
Sulfonated poly(ether ether ketone); Tungstophosphoric acid; Vanadium; Redox flow battery; Proton exchange membrane; COMPOSITE MEMBRANE; CELL;
D O I
10.1016/j.jpowsour.2010.02.008
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A novel sandwich-type sulfonated poly(ether ether ketone) (SPEEK)/tungstophosphoric acid (TPA)/polypropylene (PP) composite membrane for a vanadium redox flow battery (VRB) has been developed with improved properties: the permeability of vanadium ions is greatly reduced and the performance of the VRB cell is greatly increased. The membrane is based on a traditional SPEEK membrane embedded with TPA but PP is used to enhance the membrane for the first time. Although its voltage efficiency (VE) is a little lower than that of a Nafion 212 membrane, it is expected to have good prospects for VRB systems because of its low cost and good performance. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:4380 / 4383
页数:4
相关论文
共 8 条
  • [1] Nafion-clay nanocomposite membranes: Morphology and properties
    Alonso, Rafael Herrera
    Estevez, Luis
    Lian, Huiqin
    Kelarakis, Antonios
    Giannelis, Emmanuel P.
    [J]. POLYMER, 2009, 50 (11) : 2402 - 2410
  • [2] Sulfonated polyether ether ketone composite membrane using tungstosilicic acid supported on silica-aluminium oxide for direct methanol fuel cell (DMFC)
    Ismail, A. F.
    Othman, N. H.
    Mustafa, A.
    [J]. JOURNAL OF MEMBRANE SCIENCE, 2009, 329 (1-2) : 18 - 29
  • [3] Preparation and characterization of Nafion/SPEEK layered composite membrane and its application in vanadium redox flow battery
    Luo, Qingtao
    Zhang, Huamin
    Chen, Jian
    You, Dongjiang
    Sun, Chenxi
    Zhang, Yu
    [J]. JOURNAL OF MEMBRANE SCIENCE, 2008, 325 (02) : 553 - 558
  • [4] Evaluation of the chemical stability of some membranes in vanadium solution
    Mohammadi, T
    Skyllas-Kazacos, M
    [J]. JOURNAL OF APPLIED ELECTROCHEMISTRY, 1997, 27 (02) : 153 - 160
  • [5] Investigation on V(IV)/V(V) species in a vanadium redox flow battery
    Oriji, G
    Katayama, Y
    Miura, T
    [J]. ELECTROCHIMICA ACTA, 2004, 49 (19) : 3091 - 3095
  • [6] NEW ALL-VANADIUM REDOX FLOW CELL
    SKYLLAS-KAZACOS, M
    RYCHCIK, M
    ROBINS, RG
    FANE, AG
    GREEN, MA
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1986, 133 (05) : 1057 - 1058
  • [7] Proton conducting composite membrane from Daramic/Nafion for vanadium redox flow battery
    Tian, B
    Yan, CW
    Wang, FH
    [J]. JOURNAL OF MEMBRANE SCIENCE, 2004, 234 (1-2) : 51 - 54
  • [8] Studies on polypyrrole modified nafion membrane for vanadium redox flow battery
    Zeng, Jie
    Jiang, Chunping
    Wang, Yaohui
    Chen, Jinwei
    Zhu, Shifu
    Zhao, Beijun
    Wang, Ruilin
    [J]. ELECTROCHEMISTRY COMMUNICATIONS, 2008, 10 (03) : 372 - 375