Pd nanoparticles embedded in mesoporous carbon: A highly efficient catalyst for Suzuki-Miyaura reaction

被引：43

作者：

Zhong, Lin ^{[1
,2
]}

Chokkalingam, Anand ^{[1
]}

Cha, Wang S. ^{[1
]}

Lakhi, Kripal S. ^{[1
]}

Su, Xiangyang ^{[2
]}

Lawrence, Geoffrey ^{[1
]}

Vinu, Ajayan ^{[1
]}

机构：

[1] Univ Queensland, Australian Inst Bioengn & Nanotechnol, Brisbane, Qld 4072, Australia

[2] Sichuan Univ, Coll Chem Engn, Chengdu 610065, Sichuan, Peoples R China

来源：

CATALYSIS TODAY | 2015年 / 243卷

基金：

中国国家自然科学基金;

关键词：

Mesoporous carbon; Nanoparticles; Coupling reaction; Catalysis; DISPERSED PLATINUM NANOPARTICLES; ONE-POT SYNTHESIS; PALLADIUM CATALYSTS; COUPLING REACTIONS; ORGANIC-SYNTHESIS; MOLECULAR-SIEVES; HECK;

D O I：

10.1016/j.cattod.2014.08.038

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Mesoporous carbon functionalized with Pd nanoparticles (Pd@MC) was synthesized via one-pot method using SBA-15, furfuryl alcohol and PdCl2 as a template, a carbon source and a palladium source, respectively. The HRTEM image shows that Pd nanoparticles are homogeneously distributed on the surface of nanoporous carbon whereas the XPS spectrum of the catalyst indicates that Pd exists in the form of Pd (0). With a low loading of the catalyst (2 mol% Pd), Pd@MC shows a high conversion (100%) and selectivity for the desired product (>95%) in the Suzuki-Miyaura reactions of acyl halides with phenylboronic acid under a mild reaction condition. The catalyst was found to be highly active and no leaching in the reaction is observed. The catalyst can further be recycled for up to three times without loss of reactivity. Crown Copyright (C) 2014 Published by Elsevier B.V. All rights reserved.

引用

页码：195 / 198

页数：4

共 23 条

[11] Mesoporous carbon materials: Synthesis and modification [J].

Liang, Chengdu ;

Li, Zuojiang ;

Dai, Sheng .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (20) :3696-3717

[12] Controlled synthesis of highly dispersed platinum nanoparticles in ordered mesoporous carbon [J].

Liu, Shou-Heng ;

Lu, Rong-Feng ;

Huang, Shing-Jong ;

Lo, An-Ya ;

Chien, Shu-Hua ;

Liu, Shang-Bin .

CHEMICAL COMMUNICATIONS, 2006, (32) :3435-3437

[13] Preparation of Highly Ordered Nitrogen-Containing Mesoporous Carbon from a Gelatin Biomolecule and its Excellent Sensing of Acetic Acid [J].

Mane, Gurudas P. ;

Talapaneni, Siddulu N. ;

Anand, Chokkalingam ;

Varghese, Shaji ;

Iwai, Hideo ;

Ji, Qingmin ;

Ariga, Katsuhiko ;

Mori, Toshiyuki ;

Vinu, Ajayan .

ADVANCED FUNCTIONAL MATERIALS, 2012, 22 (17) :3596-3604

[14] Palladium Nanoparticles on Graphite Oxide and Its Functionalized Graphene Derivatives as Highly Active Catalysts for the Suzuki-Miyaura Coupling Reaction [J].

Scheuermann, Gil M. ;

Rumi, Luigi ;

Steurer, Peter ;

Bannwarth, Willi ;

Muelhaupt, Rolf .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (23) :8262-8270

[15] Partially embedded highly dispersed Pt nanoparticles in mesoporous carbon with enhanced leaching stability [J].

Scholz , Kerstin ;

Scholz, Jan ;

McQuillan, A. James ;

Wagner, Gerald ;

Klepel, Olaf .

CARBON, 2010, 48 (06) :1788-1798

[16] Recent advances in Pd/C-catalyzed coupling reactions [J].

Seki, Masahiko .

SYNTHESIS-STUTTGART, 2006, (18) :2975-2992

[17] A General Chelate-Assisted Co-Assembly to Metallic Nanoparticles-Incorporated Ordered Mesoporous Carbon Catalysts for Fischer-Tropsch Synthesis [J].

Sun, Zhenkun ;

Sun, Bo ;

Qiao, Minghua ;

Wei, Jing ;

Yue, Qin ;

Wang, Chun ;

Deng, Yonghui ;

Kaliaguine, Serge ;

Zhao, Dongyuan .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (42) :17653-17660

[18] Recent progress in polymeric palladium catalysts for organic synthesis [J].

Uozumi, Y .

IMMOBILIZED CATALYSTS: SOLID PHASES, IMMOBILIZATION AND APPLICATIONS, 2004, 242 :77-112

[19] Electrochemical degradation of 4-chlorophenol using a novel Pd/C gas-diffusion electrode [J].

Wang, Hui ;

Wang, Jianlong .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2007, 77 (1-2) :58-65

[20] Core/shell Pt/C nanoparticles embedded in mesoporous carbon as a methanol-tolerant cathode catalyst in direct methanol fuel cells [J].

Wen, Zhenhai ;

Liu, Juan ;

Li, Jinghong .

ADVANCED MATERIALS, 2008, 20 (04) :743-+

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